[(triphenylphosphine)Pd(CH₂C(CH₃)2P(t-Bu)2)(OAc)]HOAC

Base Information

• Chemical Name: [(triphenylphosphine)Pd(CH₂C(CH₃)2P(t-Bu)2)(OAc)]HOAC
• CAS No.: 1333204-21-9
• Molecular Formula: C₂H₄O₂*C₃₂H₄₄O₂P₂Pd
• Molecular Weight: 689.12
• Mol file: 1333204-21-9.mol

Synonyms:

Chemical Property of [(triphenylphosphine)Pd(CH₂C(CH₃)2P(t-Bu)2)(OAc)]HOAC

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(triphenylphosphine)Pd(CH₂C(CH₃)2P(t-Bu)2)(OAc)]HOAC

There total 2 articles about [(triphenylphosphine)Pd(CH₂C(CH₃)2P(t-Bu)2)(OAc)]HOAC which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

tri-tert-butyl phosphine (13716-12-6) + palladium diacetate (3375-31-3) + triphenylphosphine (603-35-0) → [(triphenylphosphine)Pd(CH2C(CH3)2P(t-Bu)2)(OAc)]HOAC (1333204-21-9)

Guidance literature:

In tetrahydrofuran; addn. of THF to vial with Pd(OAc)2, P(t-Bu)3 (1 equiv.) and PPh3 (1 equiv.), stirring at ambient temp. for 2 h; removal of solvent under reduced pressure, dissolving in Et2O, filtration, concn., cooling at -30°C for 4 h, addn. of pentane, cooling at-30°C for 12 h, vac. filtration, washing with cold pentane;

DOI:10.1021/om2006936

Reference yield:

bis(tri-t-butylphosphine)palladium(0) (53199-31-8) → [(triphenylphosphine)Pd(CH2C(CH3)2P(t-Bu)2)(OAc)]HOAC (1333204-21-9)

Guidance literature:

Multi-step reaction with 2 steps

1: acetic acid

2: tetrahydrofuran

In tetrahydrofuran; acetic acid;

DOI:10.1021/om2006936

upstream raw materials:

tri-tert-butyl phosphine

palladium diacetate

triphenylphosphine

bis(tri-t-butylphosphine)palladium⁽⁰⁾

Refernces