(Sp)-1,2:3,5-diisopropylidene-α-D-glucofuranosyl isopropylphenylphosphinite

Base Information

• Chemical Name: (Sp)-1,2:3,5-diisopropylidene-α-D-glucofuranosyl isopropylphenylphosphinite
• CAS No.: 184776-11-2
• Molecular Formula: C₂₁H₃₁O₆P
• Molecular Weight: 410.447
• Mol file: 184776-11-2.mol

Synonyms:

Chemical Property of (Sp)-1,2:3,5-diisopropylidene-α-D-glucofuranosyl isopropylphenylphosphinite

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (Sp)-1,2:3,5-diisopropylidene-α-D-glucofuranosyl isopropylphenylphosphinite

There total 1 articles about (Sp)-1,2:3,5-diisopropylidene-α-D-glucofuranosyl isopropylphenylphosphinite which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chloro(isopropyl)phenylphosphane (54006-34-7) + 1,2:5,6-di-O-isopropylidene-α-D-glucofuranose (582-52-5) → (Sp)-1,2:3,5-diisopropylidene-α-D-glucofuranosyl isopropylphenylphosphinite (184776-11-2,177981-02-1)

Guidance literature:

With 1,4-diaza-bicyclo[2.2.2]octane; In toluene; at -20 - 20 ℃;

DOI:10.1080/10426509608037959

Reference yield:

methyllithium (917-54-4) + (Sp)-1,2:3,5-diisopropylidene-α-D-glucofuranosyl isopropylphenylphosphinite (184776-11-2,177981-02-1) → (S)-(-)-(methyl)(phenyl)-i-propylphosphine

Guidance literature:

DOI:10.1080/10426509608037959

upstream raw materials:

chloro(isopropyl)phenylphosphane

1,2:5,6-di-O-isopropylidene-α-D-glucofuranose