dichloro(phenyl(1-pyridin-2-ylethylene)amine)palladium(II)

Base Information

• Chemical Name: dichloro(phenyl(1-pyridin-2-ylethylene)amine)palladium(II)
• CAS No.: 374724-42-2
• Molecular Formula: C₁₃H₁₂Cl₂N₂Pd
• Molecular Weight: 373.578
• Mol file: 374724-42-2.mol

Synonyms:

Chemical Property of dichloro(phenyl(1-pyridin-2-ylethylene)amine)palladium(II)

Chemical Property:

Purity/Quality:

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Useful:

Technology Process of dichloro(phenyl(1-pyridin-2-ylethylene)amine)palladium(II)

There total 1 articles about dichloro(phenyl(1-pyridin-2-ylethylene)amine)palladium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

phenyl-(1-(pyridin-2-yl)-ethylidene)-amine (17424-78-1) + cis-dichlorobis(benzonitrile)palladium(II) (14220-64-5,15617-18-2,39958-10-6) → dichloro(phenyl(1-pyridin-2-ylethylene)amine)palladium(II) (374724-42-2)

Guidance literature:

In toluene; under Ar; dropwise addn. of the amine to soln. of Pd complex at 70°C, stirring at 70°C for 2.5 h; cooled to room temp., pentane was added, ppt. was filtered off, washed with ether; elem. anal.;

DOI:10.1021/om0103097

Reference yield: 72.0%

dichloro(phenyl(1-pyridin-2-ylethylene)amine)palladium(II) (374724-42-2) + water (7732-18-5) + silver trifluoromethanesulfonate (2923-28-6) → (phenyl(1-pyridin-2-ylethylene)amine)Pd(H2O)2(trifluoromethanesulfonate)2

Guidance literature:

In dichloromethane; under Ar; addn. of Ag triflate to soln. of the Pd complex in CH2Cl2, suspn. was stirred for 3-12 h in the dark; soln. filtered, ppt. was washed with MeCN, combined filtrate evapd. to dryness under vac.; elem. anal.;

DOI:10.1021/om0103097

upstream raw materials:

phenyl-(1-(pyridin-2-yl)-ethylidene)-amine

cis-dichlorobis(benzonitrile)palladium(II)