bis(triphenylphosphine)copper(I) benzoate complex

Base Information

• Chemical Name: bis(triphenylphosphine)copper(I) benzoate complex
• CAS No.: 32335-61-8
• Molecular Formula: C₄₃H₃₅CuO₂P₂
• Molecular Weight: 709.243
• Mol file: 32335-61-8.mol

Synonyms:

Chemical Property of bis(triphenylphosphine)copper(I) benzoate complex

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of bis(triphenylphosphine)copper(I) benzoate complex

There total 5 articles about bis(triphenylphosphine)copper(I) benzoate complex which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

(triphenylphosphine)2CuCl2 (27396-56-1,38613-49-9) + benzoic acid (65-85-0,8013-63-6) → bis(triphenylphosphine)copper(I) benzoate complex (32335-61-8,69476-03-5)

Guidance literature:

In ethanol; Reflux;

DOI:10.1016/j.jorganchem.2018.10.017

Reference yield: 67.0%

9,10-phenanthrenesemiquinonatobis(triphenylphosphine)copper(I) + dibenzoyl peroxide (94-36-0) → bis(triphenylphosphine)copper(I) benzoate complex (32335-61-8,69476-03-5) + 9,10-phenanthrenequinone (84-11-7)

Guidance literature:

In dichloromethane; under Ar, at -79°C, allowed to warm up to room temp. and kept here overnight; half of the solvent stripped in vac., ether layered over the soln., standing, filtered, washed with ether, dried in vac., sepn. by washing with CH3CN; elem. anal.;

DOI:10.1016/S0020-1693(00)83682-8

Reference yield: 44.13%

copper(II) benzoate trihydrate + triphenylphosphine (603-35-0) → bis(triphenylphosphine)copper(I) benzoate complex (32335-61-8,69476-03-5)

Guidance literature:

In methanol; for 1.5h; Heating;

DOI:10.1021/acs.inorgchem.9b02172

upstream raw materials:

copper

triphenylphosphine

benzoic acid

phenyl copper

Downstream raw materials:

[(Ph₃P)₂Cu(κ²-O₂CH)]