[Zn(terephthalate)(4,4'-bipyridine)]

Base Information

• Chemical Name: [Zn(terephthalate)(4,4'-bipyridine)]
• CAS No.: 515139-30-7
• Molecular Formula: C₈H₄O₄*C₁₀H₈N₂*Zn
• Molecular Weight: 385.694
• Mol file: 515139-30-7.mol

Synonyms:

Chemical Property of [Zn(terephthalate)(4,4'-bipyridine)]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Zn(terephthalate)(4,4'-bipyridine)]

There total 2 articles about [Zn(terephthalate)(4,4'-bipyridine)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 65.0%

[2,2]bipyridinyl (366-18-7) + zinc(II) nitrate hexahydrate + terephthalic acid (100-21-0) → [Zn(terephthalate)(4,4'-bipyridine)] (515139-30-7)

Guidance literature:

With pyridine; In water; aq. mixt. contg. H2tp (0.5 mmol), Zn-contg. compd. (0.5 mmol), 4,4'-bipy(0.5 mmol), pyridine was sealed and heated to 180°C for 7 d in s tainless steel vessel; then it was cooled to 100°C and held at this temp.for 10 h; slow cooling to room temp.; crystals were collected, washed with water and dried in air; elem. anal.;

DOI:10.1039/b005438k

Reference yield:

{[Zn(1,4-benzenedicarboxylato)(2,2'-bipyridine)]·N,N-dimethylformamide}n → [Zn(terephthalate)(4,4'-bipyridine)] (515139-30-7)

Guidance literature:

With carbon dioxide; at 40 ℃; for 0.4 - 6h; under 75.0075 Torr;

DOI:10.1021/acs.cgd.1c00240

upstream raw materials:

[2,2]bipyridinyl

terephthalic acid