20,21-bis<<2-(2-hydroxyethoxy)ethoxy>methyl>-1,4,7,12,15,18-hexaoxacyclodocosa-9,20-diene-9,10-dimethanol 20,21-bis(p-toluenesulfonate)

Base Information

Chemical Name:20,21-bis<<2-(2-hydroxyethoxy)ethoxy>methyl>-1,4,7,12,15,18-hexaoxacyclodocosa-9,20-diene-9,10-dimethanol 20,21-bis(p-toluenesulfonate)
CAS No.:79289-91-1
Molecular Formula:C₄₂H₆₄O₁₈S₂
Molecular Weight:921.091
Hs Code.:

20,21-bis<<2-(2-hydroxyethoxy)ethoxy>methyl>-1,4,7,12,15,18-hexaoxacyclodocosa-9,20-diene-9,10-dimethanol 20,21-bis(p-toluenesulfonate)

Synonyms:

Suppliers and Price of 20,21-bis<<2-(2-hydroxyethoxy)ethoxy>methyl>-1,4,7,12,15,18-hexaoxacyclodocosa-9,20-diene-9,10-dimethanol 20,21-bis(p-toluenesulfonate)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 20,21-bis<<2-(2-hydroxyethoxy)ethoxy>methyl>-1,4,7,12,15,18-hexaoxacyclodocosa-9,20-diene-9,10-dimethanol 20,21-bis(p-toluenesulfonate)

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 20,21-bis<<2-(2-hydroxyethoxy)ethoxy>methyl>-1,4,7,12,15,18-hexaoxacyclodocosa-9,20-diene-9,10-dimethanol 20,21-bis(p-toluenesulfonate)

There total 9 articles about 20,21-bis<<2-(2-hydroxyethoxy)ethoxy>methyl>-1,4,7,12,15,18-hexaoxacyclodocosa-9,20-diene-9,10-dimethanol 20,21-bis(p-toluenesulfonate) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 14496-24-3
3,4-bis(hydroxymethyl)furan

: 79289-91-1,110512-26-0
20,21-bis<<2-(2-hydroxyethoxy)ethoxy>methyl>-1,4,7,12,15,18-hexaoxacyclodocosa-9,20-diene-9,10-dimethanol 20,21-bis(p-toluenesulfonate)

Guidance literature:: Multi-step reaction with 7 steps

1: 89 percent / NaH / dimethylformamide / 48 h / Ambient temperature

2: 97 percent / Dowex 50W-X₁₂ / methanol; CH₂Cl₂ / 12 h / Heating

3: 84 percent / pyridine / 12 h / 0 °C

4: 61 percent / NaH / dimethylformamide / 48 h / Ambient temperature

5: 90 percent / Dowex 50W-X₁₂ / methanol; CH₂Cl₂ / 12 h / Heating

6: 83 percent / pyridine / 12 h / 0 °C

7: 1.) LiBF₄, NaHCO₃, 2.) NaBH₄ / 1.) Pt anode / 1.) CH₃CN, H₂O, 2.) EtOH

With sodium tetrahydroborate; lithium tetrafluoroborate; Dowex 50W-X₁₂; sodium hydride; sodium hydrogencarbonate; 1.) Pt anode; In pyridine; methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ja00410a041

Reference yield:

: 79289-84-2
2,2'-(3,4-furandiylbis(methyleneoxyethyleneoxy))bis-(tetrahydro-2H-pyran)

: 79289-91-1,110512-26-0
20,21-bis<<2-(2-hydroxyethoxy)ethoxy>methyl>-1,4,7,12,15,18-hexaoxacyclodocosa-9,20-diene-9,10-dimethanol 20,21-bis(p-toluenesulfonate)

Guidance literature:: Multi-step reaction with 6 steps

1: 97 percent / Dowex 50W-X₁₂ / methanol; CH₂Cl₂ / 12 h / Heating

2: 84 percent / pyridine / 12 h / 0 °C

3: 61 percent / NaH / dimethylformamide / 48 h / Ambient temperature

4: 90 percent / Dowex 50W-X₁₂ / methanol; CH₂Cl₂ / 12 h / Heating

5: 83 percent / pyridine / 12 h / 0 °C

6: 1.) LiBF₄, NaHCO₃, 2.) NaBH₄ / 1.) Pt anode / 1.) CH₃CN, H₂O, 2.) EtOH

With sodium tetrahydroborate; lithium tetrafluoroborate; Dowex 50W-X₁₂; sodium hydride; sodium hydrogencarbonate; 1.) Pt anode; In pyridine; methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1021/ja00410a041

Reference yield:

: 79289-88-6
6,7,9,10,12,15,17,18,20,21-decahydro-13,14-bis(2-(2-((tetrahydro-2H-pyran-2-yl)oxy)ethoxy)methyl)-4H,23H-furo(3,4-i)(1,4,7,12,15,18)hexaoxacyclodocosin

: 79289-91-1,110512-26-0
20,21-bis<<2-(2-hydroxyethoxy)ethoxy>methyl>-1,4,7,12,15,18-hexaoxacyclodocosa-9,20-diene-9,10-dimethanol 20,21-bis(p-toluenesulfonate)

Guidance literature:: Multi-step reaction with 3 steps

1: 90 percent / Dowex 50W-X₁₂ / methanol; CH₂Cl₂ / 12 h / Heating

2: 83 percent / pyridine / 12 h / 0 °C

3: 1.) LiBF₄, NaHCO₃, 2.) NaBH₄ / 1.) Pt anode / 1.) CH₃CN, H₂O, 2.) EtOH

With sodium tetrahydroborate; lithium tetrafluoroborate; Dowex 50W-X₁₂; sodium hydrogencarbonate; 1.) Pt anode; In pyridine; methanol; dichloromethane;
DOI:10.1021/ja00410a041