2-phenyl-1,3,11,11c-tetraazacyclopenta[c]phenanthrene

Base Information

• Chemical Name: 2-phenyl-1,3,11,11c-tetraazacyclopenta[c]phenanthrene
• CAS No.: 1235549-30-0
• Molecular Formula: C₁₉H₁₂N₄
• Molecular Weight: 296.331
• Mol file: 1235549-30-0.mol

Synonyms:

Chemical Property of 2-phenyl-1,3,11,11c-tetraazacyclopenta[c]phenanthrene

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 2-phenyl-1,3,11,11c-tetraazacyclopenta[c]phenanthrene

There total 1 articles about 2-phenyl-1,3,11,11c-tetraazacyclopenta[c]phenanthrene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 36.0%

benzonitrile (100-47-0) + 1-amino-1,10-phenanthrolinium mesitylenesulfonate → 2-phenyl-1,3,11,11c-tetraazacyclopenta[c]phenanthrene (1235549-30-0)

Guidance literature:

With potassium hydroxide; at 20 ℃;

DOI:10.1134/S1070363210010184

Reference yield: 100.0%

copper(ll) sulfate pentahydrate + 2-phenyl-1,3,11,11c-tetraazacyclopenta[c]phenanthrene (1235549-30-0) → CuSO4(2-phenyl-1,3,11,11c-tetraazacyclopenta[c]phenanthrene)*2H2O

Guidance literature:

In ethanol; water; warm (about 50°C) soln. of Cu salt in H2O and soln. of ligand in EtOH were mixed (molar ratio Cu:ligand = 1:2); cooled to room temp.; ppt. filtered; washed (EtOH, hexane); dried (air); elem. anal.;

DOI:10.1134/S1070363210010184

Reference yield: 62.0%

hydrogenchloride (7647-01-0,15364-23-5) + 2-phenyl-1,3,11,11c-tetraazacyclopenta[c]phenanthrene (1235549-30-0) + palladium dichloride → PdCl3(2-phenyl-1,3,11,11c-tetraazacyclopenta[c]phenanthrene(+1H)

Guidance literature:

In ethanol; to soln. of PdCl2 in EtOH + 3 drops of conc. HCl added soln. of ligand in EtOH; allowed to stand for 4 h; ppt. filtered; washed (EtOH, hexane); dried (air); elem. anal.;

DOI:10.1134/S1070363210010184

upstream raw materials:

benzonitrile