diethylaminobis[N-pentafluorophenyl-N-(2-pyridyl)amino]stibane

Base Information

• Chemical Name: diethylaminobis[N-pentafluorophenyl-N-(2-pyridyl)amino]stibane
• CAS No.: 802902-73-4
• Molecular Formula: C₂₆H₁₈F₁₀N₅Sb
• Molecular Weight: 712.196
• Mol file: 802902-73-4.mol

Synonyms:

Chemical Property of diethylaminobis[N-pentafluorophenyl-N-(2-pyridyl)amino]stibane

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of diethylaminobis[N-pentafluorophenyl-N-(2-pyridyl)amino]stibane

There total 2 articles about diethylaminobis[N-pentafluorophenyl-N-(2-pyridyl)amino]stibane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

antimony tris(diethylamide) (34832-65-0) + 2-( 2,3,4,5,6-pentafluoroanilino)pyridine (196189-94-3) → diethylaminobis[N-pentafluorophenyl-N-(2-pyridyl)amino]stibane (802902-73-4)

Guidance literature:

In toluene; (Ar), 2 equiv. of amine in toluene added dropwise at -78°C to a stirrred stibane complex in toluene, stirred at room temp. for 12 h; evapd.(vac.), elem. anal.;

DOI:10.1002/ejic.200400074

Reference yield:

antimony tris(diethylamide) (34832-65-0) + 2-( 2,3,4,5,6-pentafluoroanilino)pyridine (196189-94-3) → bis(diethylamino)[N-pentafluorophenyl-N-(2-pyridyl)amino]stibane (802902-69-8) + diethylaminobis[N-pentafluorophenyl-N-(2-pyridyl)amino]stibane (802902-73-4)

Guidance literature:

In toluene; (Ar), 1 equiv. of amine in toluene added dropwise at -78°C to a stirrred stibane complex in toluene, stirred at room temp. for 12 h; evapd.(vac.), elem. anal.;

DOI:10.1002/ejic.200400074

Reference yield: 71.0%

diethylaminobis[N-pentafluorophenyl-N-(2-pyridyl)amino]stibane (802902-73-4) → [N-(2-diethylamino-3,4,5,6-tetrafluorophenyl)-N-(2-pyridyl)amino][N-(pentafluorophenyl)-N-(2-pyridyl)amino]fluorostibane (802902-76-7)

Guidance literature:

In toluene; (Ar), stibane in toluene stirred for 21 d at room temp.; crystd.(toluene/n-pentane, -30°C) overnight, elem. anal.;

DOI:10.1002/ejic.200400074

upstream raw materials:

antimony tris(diethylamide)

2-( 2,3,4,5,6-pentafluoroanilino)pyridine

Downstream raw materials:

[N-(2-diethylamino-3,4,5,6-tetrafluorophenyl)-N-(2-pyridyl)amino][N-(pentafluorophenyl)-N-(2-pyridyl)amino]fluorostibane