4-((E)-2-(1-methyl-1H-benzo[d]imidazol-2-yl)vinyl)-N-(4-((E)-2-(1-methyl-1H-benzo[d]imidazol-2-yl)vinyl)phenyl)-N-phenylaniline

Base Information

• Chemical Name: 4-((E)-2-(1-methyl-1H-benzo[d]imidazol-2-yl)vinyl)-N-(4-((E)-2-(1-methyl-1H-benzo[d]imidazol-2-yl)vinyl)phenyl)-N-phenylaniline
• CAS No.: 1449747-83-4
• Molecular Formula: C₃₈H₃₁N₅
• Molecular Weight: 557.698
• Mol file: 1449747-83-4.mol

Synonyms:

Chemical Property of 4-((E)-2-(1-methyl-1H-benzo[d]imidazol-2-yl)vinyl)-N-(4-((E)-2-(1-methyl-1H-benzo[d]imidazol-2-yl)vinyl)phenyl)-N-phenylaniline

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 4-((E)-2-(1-methyl-1H-benzo[d]imidazol-2-yl)vinyl)-N-(4-((E)-2-(1-methyl-1H-benzo[d]imidazol-2-yl)vinyl)phenyl)-N-phenylaniline

There total 3 articles about 4-((E)-2-(1-methyl-1H-benzo[d]imidazol-2-yl)vinyl)-N-(4-((E)-2-(1-methyl-1H-benzo[d]imidazol-2-yl)vinyl)phenyl)-N-phenylaniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 85.0%

4,4'-diformyltriphenylamine (53566-95-3) + ((1-methyl-1H-benzo[d]imidazol-2-yl)methyl)triphenylphosphonium chloride (68426-76-6) → 4-((E)-2-(1-methyl-1H-benzo[d]imidazol-2-yl)vinyl)-N-(4-((E)-2-(1-methyl-1H-benzo[d]imidazol-2-yl)vinyl)phenyl)-N-phenylaniline (1449747-83-4)

Guidance literature:

With methanol; sodium methylate;

DOI:10.1021/ja404422z

Reference yield:

2-chloromethyl-1-methyl-1H-benzimidazole (4760-35-4) → 4-((E)-2-(1-methyl-1H-benzo[d]imidazol-2-yl)vinyl)-N-(4-((E)-2-(1-methyl-1H-benzo[d]imidazol-2-yl)vinyl)phenyl)-N-phenylaniline (1449747-83-4)

Guidance literature:

Multi-step reaction with 2 steps

1: toluene / Reflux

2: sodium methylate; methanol

With methanol; sodium methylate; In toluene; 2: |Wittig Olefination;

DOI:10.1021/ja404422z

Reference yield:

N-methyl-1,2-phenylenediamine (4760-34-3) → 4-((E)-2-(1-methyl-1H-benzo[d]imidazol-2-yl)vinyl)-N-(4-((E)-2-(1-methyl-1H-benzo[d]imidazol-2-yl)vinyl)phenyl)-N-phenylaniline (1449747-83-4)

Guidance literature:

Multi-step reaction with 3 steps

1: hydrogenchloride / water / Reflux

2: toluene / Reflux

3: sodium methylate; methanol

With hydrogenchloride; methanol; sodium methylate; In water; toluene; 3: |Wittig Olefination;

DOI:10.1021/ja404422z

upstream raw materials:

2-chloromethyl-1-methyl-1H-benzimidazole

4,4'-diformyltriphenylamine

((1-methyl-1H-benzo[d]imidazol-2-yl)methyl)triphenylphosphonium chloride

N-methyl-1,2-phenylenediamine