fac-[Re(2,2'-bipyridine)(CO)3(tris(4-methylphenyl)phosphine)]PF₆

Base Information

• Chemical Name: fac-[Re(2,2'-bipyridine)(CO)3(tris(4-methylphenyl)phosphine)]PF₆
• CAS No.: 847050-81-1
• Molecular Formula: C₃₄H₂₉N₂O₃PRe*F₆P
• Molecular Weight: 875.761
• Mol file: 847050-81-1.mol

Synonyms:

Chemical Property of fac-[Re(2,2'-bipyridine)(CO)3(tris(4-methylphenyl)phosphine)]PF₆

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of fac-[Re(2,2'-bipyridine)(CO)3(tris(4-methylphenyl)phosphine)]PF₆

There total 1 articles about fac-[Re(2,2'-bipyridine)(CO)3(tris(4-methylphenyl)phosphine)]PF₆ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

ammonium hexafluorophosphate + fac-rhenium(I)(chloro)tri(carbonyl)(2,2'-bipyridine) (52064-98-9,55658-96-3,958643-91-9) + silver trifluoromethanesulfonate (2923-28-6) + Tri(p-tolyl)phosphine (1038-95-5,218281-19-7) → fac-[Re(2,2'-bipyridine)(CO)3(tris(4-methylphenyl)phosphine)]PF6 (847050-81-1) + silver(I) chloride

Guidance literature:

In acetone; under N2 atm. soln. fac-Re(bpy)(CO)3Cl and CF3SO3Ag in acetone was refluxed for 5 h in darkness, ppt. was filtered, phosphine was added, refluxed overnight in darkness, evapd. in vacuo, recrystd. from CH2Cl2, dissolved in MeOH, added to NH4PF6 in MeOH; ppt. was filtered, washed with water and dried in vacuo;

DOI:10.1039/b407947g

upstream raw materials:

fac-rhenium(I)(chloro)tri(carbonyl)(2,2'-bipyridine)

silver trifluoromethanesulfonate

Tri(p-tolyl)phosphine