cobalt(III) 8-hydroxyquinoline

Base Information

Chemical Name:cobalt(III) 8-hydroxyquinoline
CAS No.:14592-28-0
Molecular Formula:C₂₇H₁₈CoN₃O₃
Molecular Weight:491.451
Hs Code.:

Synonyms:

Suppliers and Price of cobalt(III) 8-hydroxyquinoline

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of cobalt(III) 8-hydroxyquinoline

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of cobalt(III) 8-hydroxyquinoline

There total 3 articles about cobalt(III) 8-hydroxyquinoline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 14.6%

: 148-24-3,24804-14-6
8-quinolinol

: cobalt(II) chloride hexahydrate

: 14592-28-0,87583-62-8,87583-61-7
cobalt(III) 8-hydroxyquinoline

: 10534-89-1
hexammine cobalt(III) chloride

: {Co(oxin)(NH₃)4}Cl₂*H₂O

: diamminebis(8-quinolinato)cobalt(III) chloride hydrate

Guidance literature:: With NH₃; H₂O₂; In methanol; water; 28 % ammonia soln. added to aq. CoCl2*6H2O and 30% H2O2 added to soln. at 0°C, methanol soln. of 8-quinolinol added for 90 min at 60°C, mixt. refluxed for 1 d; Co(C9H6NO)3 filtered, filtrate concd., tetra- and diammine complex extd. with methanol from dried mixt., soln. chromd., diammine recrystd. fromMeOH-H2O, eluent switched to water, eluate concd. dried over silica gel; tetraammine ppt. by addn. of acetone;
DOI:10.1246/cl.1980.1555

Reference yield: 13.27%

: 148-24-3,24804-14-6
8-quinolinol

: 13408-72-5,14040-32-5,14040-33-6,20594-10-9,20594-11-0
trans-dichlorobis(ethylenediamine)cobalt(III) chloride

: 14592-28-0,87583-62-8,87583-61-7
cobalt(III) 8-hydroxyquinoline

: 13408-73-6
[tris(1,2-diaminoethane)cobalt(III)] chloride

: bis(ethylenediamine)(8-quinolinato)cobalt(III) chloride dihydrate

: ethylenediaminebis(8-quinolinato)cobalt(III) chloride dihydrate

Guidance literature:: With Ag₂O; H₂O; In methanol; reaction of starting Co complex with Ag2O, slow addn. of 8-quinolinol CH3OH soln. to resulting aq. soln., stirring for 2 d at 60°C; filtration, vac. concn., drying over silica gel, extn. (dry C2H5OH), chromy. (Al2O3, C2H5OH/acetone), recrystn. twice (C2H5OH/ether), extn. after drying (dry CH3OH), recrystn. twice (H2O/acetone), elem. anal.;
DOI:10.1246/bcsj.54.2972

Reference yield:

: 148-24-3,24804-14-6
8-quinolinol

: cis-dichlorobis(ethylenediamine)cobalt(III) chloride

: 14592-28-0,87583-62-8,87583-61-7
cobalt(III) 8-hydroxyquinoline

: 13408-73-6
[tris(1,2-diaminoethane)cobalt(III)] chloride

: bis(ethylenediamine)(8-quinolinato)cobalt(III) chloride dihydrate

: ethylenediaminebis(8-quinolinato)cobalt(III) chloride dihydrate

Guidance literature:: With Ag₂O; H₂O; In methanol; reaction of starting Co complex with Ag2O, slow addn. of 8-quinolinol CH3OH soln. to resulting aq. soln., stirring for 2 d at 60°C; filtration, vac. concn., drying over silica gel, extn. (dry C2H5OH), chromy. (Al2O3, C2H5OH/acetone), recrystn. twice (C2H5OH/ether), extn. after drying (dry CH3OH), recrystn. twice (H2O/acetone), elem. anal.;
DOI:10.1246/bcsj.54.2972