copper(2+) 6-{(E)-[(3-{[(E)-piperidin-1-id-2-ylmethylidene]amino}propyl)imino]methyl}-2H-pyridin-1-ide - trihydroxy-lambda~3~-chlorane oxide (1:1:1)

Base Information

• Chemical Name: copper(2+) 6-{(E)-[(3-{[(E)-piperidin-1-id-2-ylmethylidene]amino}propyl)imino]methyl}-2H-pyridin-1-ide - trihydroxy-lambda~3~-chlorane oxide (1:1:1)
• CAS No.: 15772-23-3
• Molecular Formula: C₁₅H₁₆Cl₂CuN₄O₈
• Molecular Weight: 514.766
• Mol file: 15772-23-3.mol

Synonyms:

Chemical Property of copper(2+) 6-{(E)-[(3-{[(E)-piperidin-1-id-2-ylmethylidene]amino}propyl)imino]methyl}-2H-pyridin-1-ide - trihydroxy-lambda~3~-chlorane oxide (1:1:1)

Chemical Property:

• Vapor Pressure: 3.45E-09mmHg at 25°C

Purity/Quality:

85.0-99.8% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of copper(2+) 6-{(E)-[(3-{[(E)-piperidin-1-id-2-ylmethylidene]amino}propyl)imino]methyl}-2H-pyridin-1-ide - trihydroxy-lambda~3~-chlorane oxide (1:1:1)

There total 3 articles about copper(2+) 6-{(E)-[(3-{[(E)-piperidin-1-id-2-ylmethylidene]amino}propyl)imino]methyl}-2H-pyridin-1-ide - trihydroxy-lambda~3~-chlorane oxide (1:1:1) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

pyridine-2-carbaldehyde (1121-60-4) + copper(II) perchlorate hexahydrate + Trimethylenediamine (109-76-2,54018-94-9) → Cu[(C5H4NCHN)2C3H6](ClO4)2 (15772-23-3)

Guidance literature:

In neat (no solvent); ligands mixed 1:2, refluxed for 2 h, treated wirh copper salt; recrystd.(CH3OH);

DOI:10.1016/S0277-5387(02)01435-3

Reference yield: 75.0%

Cu[CH3COCHCCH3NC3H6NCHC5H4N](1+)*ClO4(1-)=Cu[CH3COCHCCH3NC3H6NCHC5H4N]ClO4 → copper acetylacetonate + Cu[(C5H4NCHN)2C3H6](ClO4)2 (15772-23-3)

Guidance literature:

With HClO₄; copper(II) perchlorate hexahydrate; In methanol; water; byproducts: NH2C3H6NH2; complex in CH3OH-H2O 9:1 v/v, treated with two drops of HClO4 , refluxedfor 10 h; evapd., cooled to room temp.;

DOI:10.1016/S0277-5387(02)01435-3

Reference yield:

pyridine-2-carbaldehyde (1121-60-4) + copper(II) perchlorate hexahydrate + 8-amino-4-methyl-5-azaoct-3-ene-2-one → Cu[(C5H4NCHN)2C3H6](ClO4)2 (15772-23-3)

Guidance literature:

In methanol; acetonitrile; ligand in methanol mixed with aldehyde, warmed at 50-60°C for 1 h, cooled to room temp., treated with copper salt in methanol, reacted for 1 h; filtered, recrystd.(CH3CN-CH3OH 1:1 v/v), elem. anal.;

DOI:10.1016/S0277-5387(02)01435-3

upstream raw materials:

pyridine-2-carbaldehyde

Trimethylenediamine