(C₅H₅)Fe(C₅H₄CH(C₆H₅)S(CH₂)2COOH)

Base Information

• Chemical Name: (C₅H₅)Fe(C₅H₄CH(C₆H₅)S(CH₂)2COOH)
• CAS No.: 174535-47-8
• Molecular Formula: C₂₀H₂₀FeO₂S
• Molecular Weight: 380.291
• Mol file: 174535-47-8.mol

Synonyms:

Chemical Property of (C₅H₅)Fe(C₅H₄CH(C₆H₅)S(CH₂)2COOH)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (C₅H₅)Fe(C₅H₄CH(C₆H₅)S(CH₂)2COOH)

There total 1 articles about (C₅H₅)Fe(C₅H₄CH(C₆H₅)S(CH₂)2COOH) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

1-ferrocenylphenylmethanol + 3-mercaptopropionic acid (107-96-0) → (C5H5)Fe(C5H4CH(C6H5)S(CH2)2COOH) (174535-47-8)

Guidance literature:

With potassium hydroxide; trifluoroacetic acid; In acetone; addn. of 1.1 equiv. of mercapto-acid to Fe-complex soln., cooling to 0°C, addn. of CF3COOH, standing (room temp., overnight); addn. of 5% aq. KOH, treatment with CH2Cl2, addn. of few drops H3PO4 to aq. layer, extn. into CH2Cl2, shaking of extract with H2O, drying (MgSO4), evapn., recrystn. (hexane/C6H6 or EtOAc, not specified); elem. anal.;

DOI:10.1016/0022-328X(95)05745-B

Reference yield: 70.0%

diazomethane (186581-53-3,908094-01-9,334-88-3) + (C5H5)Fe(C5H4CH(C6H5)S(CH2)2COOH) (174535-47-8) → (C5H5)Fe(C5H4CH(C6H5)S(CH2)2COOCH3) (174535-52-5)

Guidance literature:

In methanol; diethyl ether; mixing Fe-complex (in MeOH) with diazomethane (in ether), standing (refrigerator, 12 h); evapn., TLC (SiO2, C6H6/EtOH); elem. anal.;

DOI:10.1016/0022-328X(95)05745-B

upstream raw materials:

3-mercaptopropionic acid

Downstream raw materials:

(C₅H₅)Fe(C₅H₄CH(C₆H₅)S(CH₂)2COOCH₃)