⁽⁵⁷⁾Fe(tetraphenylporphorin)

Base Information

• Chemical Name: ⁽⁵⁷⁾Fe(tetraphenylporphorin)
• CAS No.: 124419-55-2
• Molecular Formula: C₄₄H₂₈FeN₄
• Molecular Weight: 669.733
• Mol file: 124419-55-2.mol

Synonyms:

Chemical Property of ⁽⁵⁷⁾Fe(tetraphenylporphorin)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of ⁽⁵⁷⁾Fe(tetraphenylporphorin)

There total 2 articles about ⁽⁵⁷⁾Fe(tetraphenylporphorin) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

[57Fe(meso-tetraphenylporphyrinato)]2O → (57)Fe(tetraphenylporphorin) (124419-55-2)

Guidance literature:

With ethanethiol; In benzene; for 24h; Inert atmosphere; Schlenk technique;

DOI:10.1021/ic301719v

Reference yield:

ferric oxide + TPP (20998-75-8) → (57)Fe(tetraphenylporphorin) (124419-55-2)

Guidance literature:

With hydrogenchloride; chlorobenzene; In hydrogenchloride; chlorobenzene; Fe-compd. dissolved in hot, concd. HCl, mixt. taken to almost dryness, addn. of chlorobenzene, heated to reflux, distn., temp. droped to 70°C, addn. of ligand in chlorobenzene under Ar, reaction time 4-16h; solvent evapd., dissolved in toluene, extd. (H2O) washed (HCl, water), dried (Na2SO4), solvent evapd., recrystd. (CH2Cl2/hexane);

Reference yield:

(57)Fe(tetraphenylporphorin) (124419-55-2) + carbon monoxide (201230-82-2) + trimethylphosphane (594-09-2) → {(C6H5)4C20H8N4(57)Fe(P(CH3)3)(CO)}

Guidance literature:

In toluene; (Ar); CO gas bubling through react. mixture, stirring (15 min); solvent removing (reduced pressure);

DOI:10.1021/ja00141a027

upstream raw materials:

TPP