trans-4-t-butyl-1-chloro-1-nitrocyclohexane

Base Information

• Chemical Name: trans-4-t-butyl-1-chloro-1-nitrocyclohexane
• CAS No.: 82992-53-8
• Molecular Formula: C₁₀H₁₈ClNO₂
• Molecular Weight: 219.711
• Mol file: 82992-53-8.mol

Synonyms:

Chemical Property of trans-4-t-butyl-1-chloro-1-nitrocyclohexane

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-4-t-butyl-1-chloro-1-nitrocyclohexane

There total 4 articles about trans-4-t-butyl-1-chloro-1-nitrocyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

4-tert-butylcyclohexanone oxime (4701-98-8) → 4-tert-butyl-1-chloro-1-nitrocyclohexane (75107-61-8,82992-53-8,82992-54-9)

Guidance literature:

With sodium hypochlorite; In water; for 3h; Sonication;

DOI:10.1007/BF03246563

Reference yield: 54.0%

4-tert-butylcyclohexanone oxime (4701-98-8) → 4-tert-butyl-1-chloro-1-nitrocyclohexane (75107-61-8,82992-53-8,82992-54-9) + 4-tercbutyl-cyclohexanone (98-53-3)

Guidance literature:

With chloroperoxidase from fungus Caldaromyces fumago; potassium chloride; dihydrogen peroxide; In water; for 4h;

DOI:10.1021/jo961215n

Reference yield:

4-tert-butyl-1-chloro-1-nitrosocyclohexane (923947-85-7) → 4-tert-butyl-1-chloro-1-nitrocyclohexane (75107-61-8,82992-53-8,82992-54-9)

Guidance literature:

With sodium hypochlorite; tetra(n-butyl)ammonium hydrogensulfate; In benzene; at 23 ℃; for 1.3h; Yield given;

DOI:10.1016/S0040-4039(01)83928-9

upstream raw materials:

4-tert-butyl-1-chloro-1-nitrosocyclohexane

4-tert-butylcyclohexanone oxime

Downstream raw materials:

c-4-t-butyl-1-(1-methyl-1-nitroethyl)-r-1-nitrocyclohexane

t-4-t-butyl-1-(1-methyl-1-nitroethyl)-r-1-nitrocyclohexane

4-t-butyl-1-nitrocyclohexane

c-4-t-butyl-r-1-nitro-1-(p-nitrophenyl)cyclohexane