{tetrakis(2,6-dichlorophenyl)porphinato}iron(III) perchlorate

Base Information

• Chemical Name: {tetrakis(2,6-dichlorophenyl)porphinato}iron(III) perchlorate
• CAS No.: 110488-15-8
• Molecular Formula: C₄₄H₂₀Cl₉FeN₄O₄
• Molecular Weight: 1043.59
• Mol file: 110488-15-8.mol

Synonyms:

Chemical Property of {tetrakis(2,6-dichlorophenyl)porphinato}iron(III) perchlorate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of {tetrakis(2,6-dichlorophenyl)porphinato}iron(III) perchlorate

There total 2 articles about {tetrakis(2,6-dichlorophenyl)porphinato}iron(III) perchlorate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

perchloric acid (7601-90-3) + hydroxo(5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrinato)iron(III) (98715-91-4) → {tetrakis(2,6-dichlorophenyl)porphinato}iron(III) perchlorate (113859-72-6,110488-15-8)

Guidance literature:

In acetonitrile; addn. of HClO4 in CH3CN to a dispersion of (Cl8TPP)Fe(OH) in CH3CN; solvent evapd. below 10 ° C; formed crystals collected and dried under vacuum at room temp.; elem. anal.;

DOI:10.1021/ja00216a020

Reference yield:

5,10,15,20-tetra(2',6'-dichlorophenyl)porphyrinatoiron(III) chloride (91042-27-2,186099-12-7) + silver perchlorate → {tetrakis(2,6-dichlorophenyl)porphinato}iron(III) perchlorate (113859-72-6,110488-15-8)

Guidance literature:

In dichloromethane;

DOI:10.1039/c1cc13574k

Reference yield:

{tetrakis(2,6-dichlorophenyl)porphinato}iron(III) perchlorate (113859-72-6,110488-15-8) → [Fe(IV)=O(5,10,15,20-tetrakis(2,6-dichlorophenyl)porphinate)](1+)

Guidance literature:

With m-ClPhC(O)OOH; In acetonitrile; byproducts: m-ClPhC(O)OH, ClO4(1-); components mixed at -35 ° C;

DOI:10.1021/ja00216a020

upstream raw materials:

perchloric acid

hydroxo(5,10,15,20-tetrakis(2,6-dichlorophenyl)porphyrinato)iron(III)

5,10,15,20-tetra(2',6'-dichlorophenyl)porphyrinatoiron(III) chloride

Downstream raw materials:

Fe(IV)(=O)(5,10,15,20-tetrakis(2,6-dichlorophenyl)porphinate)