[iridium(I)(1,5-cyclooctadien)(trimethylsiloxide)(P(cyclohexyl)3)]

Base Information

Chemical Name:[iridium(I)(1,5-cyclooctadien)(trimethylsiloxide)(P(cyclohexyl)3)]
CAS No.:463967-39-7
Molecular Formula:C₂₉H₅₄IrOPSi
Molecular Weight:670.026
Hs Code.:

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Chemical Property of [iridium(I)(1,5-cyclooctadien)(trimethylsiloxide)(P(cyclohexyl)3)]

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Technology Process of [iridium(I)(1,5-cyclooctadien)(trimethylsiloxide)(P(cyclohexyl)3)]

There total 1 articles about [iridium(I)(1,5-cyclooctadien)(trimethylsiloxide)(P(cyclohexyl)3)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 70.0%

: 448963-53-9
[iridium(I)(1,5-cyclooctadien)(trimethylsiloxide)]2

: 2622-14-2
tricyclohexylphosphine

: 463967-39-7
[iridium(I)(1,5-cyclooctadien)(trimethylsiloxide)(P(cyclohexyl)3)]

Guidance literature:: In pentane; under Ar; Ir-contg. compd. (0.39 mmol) and PCy3 (0.79 mmol) were placed in a Schlenk flask; the react. was carried out in C5H12 at room temp. for 24 h; 1/3 of the solvent was evapd. and the concd. soln. was left to crystallize for 24 h at -20°C and at -35 - -30°C for 1 h; the liq. was decanted and the ppt. was dried under vac.;
DOI:10.1016/S0020-1693(02)00855-1

Reference yield: 70.0%

: 463967-39-7
[iridium(I)(1,5-cyclooctadien)(trimethylsiloxide)(P(cyclohexyl)3)]

: 201230-82-2
carbon monoxide

: 872142-38-6
Ir(CO)2(P(C₆H₁₁)3)(OSi(CH₃)3)

Guidance literature:: In benzene; byproducts: cyclooctadiene; (Schlenk, Ar) to a stirred soln. of complex in deoxygenated benzene CO was introduced, the reaction was carried out for 0.5 h at rom temp.; filtered off, evapd., the solid was dissolved in pentane, cooled to -20°C, crystals were washed with two small portions of pentane at -60°C, dried under vac.; elem. anal.;
DOI:10.1021/om050478h