W(CO)5((CH₃)3SnS(C₆H₅))

Base Information

• Chemical Name: W(CO)5((CH₃)3SnS(C₆H₅))
• CAS No.: 86774-15-4
• Molecular Formula: C₁₄H₁₄O₅SSnW
• Molecular Weight: 596.888
• Mol file: 86774-15-4.mol

Synonyms:

Chemical Property of W(CO)5((CH₃)3SnS(C₆H₅))

Chemical Property:

Purity/Quality:

Safty Information:

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Useful:

Technology Process of W(CO)5((CH₃)3SnS(C₆H₅))

There total 1 articles about W(CO)5((CH₃)3SnS(C₆H₅)) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 43.0%

tungsten hexacarbonyl (14040-11-0) + (phenylthio)trimethylstannane (1007-27-8) → W(CO)5((CH3)3SnS(C6H5)) (86774-15-4)

Guidance literature:

In tetrahydrofuran; Irradiation (UV/VIS); under N2 atm. soln. W(CO)6 in THF irradiated with 100 W uv lamp for 4 h, soln. chilled rapidly to 0°C, Me3SnSPh added, soln. stirred briefly, stored at -20°C in the dark overnight; soln. filtered, evapd. in vacuo at 40°C, residue extd. with hexane, extracts combined, concd., chromed. on Al2O3 with hexane, eluate evapd. to dryness, W(CO)6 sublimed at 40°C, residue recrystd. from hexane; elem. anal.;

upstream raw materials:

tungsten hexacarbonyl

(phenylthio)trimethylstannane

Refernces