1007-27-8Relevant academic research and scientific papers
Novel room light-induced disproportionation reaction of organo-ditin and -dilead compounds with organic dichalcogenides: An efficient salt-free route to organo-tin and -lead chalcogenides
Mirzaei, Farzad,Han, Li-Biao,Tanaka, Masato
, p. 657 - 658 (2007/10/03)
Disproportionation of organo-ditin and -dilead compounds (R3M)2 (M = Sn, Pb) with organic dichalcogenides (R'Z)2 (Z = S, Se, Te) is efficiently promoted by room light to produce the corresponding organo-tin and -lead chalc
Thioether complexes of tungsten hexacarbonyl
Lucas, C. Robert
, p. 1758 - 1763 (2007/10/02)
The preparation of a series of organic and organometallic thioethers R3MSR' (M = C,Si,Ge, or Sn) is reported.From these, several new compounds of type 1 are synthesized, some of which contain para-substituted aryl functions for R and R'.In hexane solution in the carbonyl streching region of the ir the uv there is evidence for a degree of multiple bonding, at least in the M - S - WW - CO portion of these molecules.Multiple bonding extending into aromatic R or R'is small or non-existent and cannot be assessed precisely because of spontaneous decomposition of the complexes.All the complexes undergo a thermally initiated decomposition, the case of which depends on the nature of R, R', and M.The unusual W(I) thiolate cis-2 is the termal decomposition product.
