mer-Ru((9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)-κ2Si,Si)(CO)3(tricyclohexylphosphane)

Base Information

• Chemical Name: mer-Ru((9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)-κ2Si,Si)(CO)3(tricyclohexylphosphane)
• CAS No.: 779332-42-2
• Molecular Formula: C₄₀H₅₇O₄PRuSi₂
• Molecular Weight: 790.105
• Mol file: 779332-42-2.mol

Synonyms:

Chemical Property of mer-Ru((9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)-κ2Si,Si)(CO)3(tricyclohexylphosphane)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of mer-Ru((9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)-κ2Si,Si)(CO)3(tricyclohexylphosphane)

There total 3 articles about mer-Ru((9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)-κ2Si,Si)(CO)3(tricyclohexylphosphane) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 84.0%

Ru((9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)-κ2Si,Si)(CO)(tricyclohexylphosphine) (1013107-53-3,779332-40-0) + carbon monoxide (201230-82-2) → mer-Ru((9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)-κ2Si,Si)(CO)3(tricyclohexylphosphane) (779332-42-2)

Guidance literature:

In dichloromethane; introduction of CO into soln. of Ru complex in CH2Cl2 at room temp.;

DOI:10.1021/om049379e

Reference yield: 84.0%

[Ru((9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl))(CO)(PCy3)] + carbon monoxide (201230-82-2) → mer-Ru((9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)-κ2Si,Si)(CO)3(tricyclohexylphosphane) (779332-42-2)

Guidance literature:

In dichloromethane; (Ar); soln. of Ru complex in CH2Cl2 in Schlenk tube was placed in liq. N2; evacuated; CO was added; warmed to room temp.; stirred for 1 h; volatiles removed (vac.); washed (hexane); dried (vac.); elem. anal.;

DOI:10.1021/om701194e

Reference yield:

[Ru((9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl))(CO)(PCy3)] + carbon monoxide (201230-82-2) → mer-Ru((9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)-κ2Si,Si)(CO)3(tricyclohexylphosphane) (779332-42-2) + [Ru((9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl))(CO)2(PCy3)] (779332-41-1)

Guidance literature:

In dichloromethane; (Ar); soln. of Ru complex in CH2Cl2 was treated with CO (1.6 equiv.) at room temp.; vigorously stirred; NMR monitoring; not isolated;

DOI:10.1021/om701194e

upstream raw materials:

Ru((9,9-dimethylxanthene-4,5-diyl)bis(dimethylsilyl)-κ2Si,Si)(CO)(tricyclohexylphosphine)

carbon monoxide