trans-carbonylchloro-bis(tri-isopropylphosphine)iridium(I)

Base Information

Chemical Name:trans-carbonylchloro-bis(tri-isopropylphosphine)iridium(I)
CAS No.:49548-57-4
Molecular Formula:C₁₉H₄₂ClIrOP₂
Molecular Weight:576.162
Hs Code.:

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Chemical Property of trans-carbonylchloro-bis(tri-isopropylphosphine)iridium(I)

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Technology Process of trans-carbonylchloro-bis(tri-isopropylphosphine)iridium(I)

There total 1 articles about trans-carbonylchloro-bis(tri-isopropylphosphine)iridium(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: chlorobis(cyclooctene)-iridium(I) dimer

: 104-55-2
3-phenyl-propenal

: 6476-36-4
tris(1-methylethyl)phosphine

: [IrH(Cl)(κ2(C,O)-C(Me)=CHCH=O)(P(i)Pr3)2]

: 49548-57-4,23368-25-4
trans-carbonylchloro-bis(tri-isopropylphosphine)iridium(I)

Guidance literature:: In toluene; byproducts: styrene; (Ar); addn. of phosphine to a suspn. of iridium complex in toluene, addn. of alkene, stirring at 80°C for 2 h, cooling to 20°C; evapn., analyzed by NMR;
DOI:10.1021/om0505099

Reference yield: 58.0%

: 49548-57-4,23368-25-4
trans-carbonylchloro-bis(tri-isopropylphosphine)iridium(I)

: 4440-01-1
lithium phenylacetylide

: 95762-57-5
[Ir(C₂C₆H₅)(CO)(P(CH(CH₃)2)3)2]

Guidance literature:: In diethyl ether; addn. of LiC2Ph to a suspn. of the chloro Ir complex in ether under N2,vigorous stirring (3 h) yielding an orange soln. and a colourless ppt.; sepn. of the ppt., evapn. of the solvent (vac.) yields a yellow oil; dissolution in a few pentane, chromy. (Al2O3), concn., crystn. (-70°C), filtration, drying (high vac.); elem. anal.;