tritylglycerol

Base Information

• Chemical Name: tritylglycerol
• CAS No.: 118014-34-9
• Molecular Formula: C₂₂H₂₂O₃
• Molecular Weight: 334.415
• Mol file: 118014-34-9.mol

Synonyms:

Chemical Property of tritylglycerol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of tritylglycerol

There total 12 articles about tritylglycerol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

1-hydroxy-3-(triphenylmethoxy)propan-2-one (121269-73-6) → tritylglycerol (16975-62-5,17327-05-8,118014-34-9,18325-46-7)

Guidance literature:

With hydrogen; Ru₂Cl₄{2,2'-bis(diphenylphosphino)-1,1'-binaphthyl}2*N(C₂H₅)3; In dichloromethane; at 20 ℃; for 72h; under 73550.8 Torr; var. cat.: _n; var. time;

DOI:10.1002/hlca.19930760620

Reference yield: 85.0%

trityl chloride (76-83-5) + glycerol (56-81-5,25618-55-7,64333-26-2,8013-25-0) → tritylglycerol (16975-62-5,17327-05-8,118014-34-9,18325-46-7)

Guidance literature:

With dmap; triethylamine; In tetrahydrofuran; at 20 ℃; for 12h;

DOI:10.1039/c4cc07538b

Reference yield: 82.0%

2,2-dimethyl-4-trityloxymethyl-[1,3]dioxolane (5330-64-3) → tritylglycerol (16975-62-5,17327-05-8,118014-34-9,18325-46-7)

Guidance literature:

With lanthanum(III) nitrate; In acetonitrile; for 5h; Heating;

DOI:10.1016/j.tetlet.2005.08.081

upstream raw materials:

1,2-bis-stearoyloxy-3-trityloxy-propane

(+/-)-3-triphenylmethoxy-1-stearoyloxy-propanol-⁽²⁾

trityl chloride

glycerol

Downstream raw materials:

1,2-bis-benzoyloxy-3-trityloxy-propane

1,2-bis-elaidoyloxy-3-trityloxy-propane

1,2-bis-stearoyloxy-3-trityloxy-propane

1,2-bis-palmitoyloxy-3-trityloxy-propane