ReH(CO)3((C₆H₅)2PO(CH₂)3OP(C₆H₅)2)

Base Information

Chemical Name:ReH(CO)3((C₆H₅)2PO(CH₂)3OP(C₆H₅)2)
CAS No.:870466-54-9
Molecular Formula:C₃₀H₂₇O₅P₂Re
Molecular Weight:715.696
Hs Code.:

ReH(CO)3((C<sub>6</sub>H<sub>5</sub>)2PO(CH<sub>2</sub>)3OP(C<sub>6</sub>H<sub>5</sub>)2)

Synonyms:

Suppliers and Price of ReH(CO)3((C₆H₅)2PO(CH₂)3OP(C₆H₅)2)

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of ReH(CO)3((C₆H₅)2PO(CH₂)3OP(C₆H₅)2)

Chemical Property:

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Technology Process of ReH(CO)3((C₆H₅)2PO(CH₂)3OP(C₆H₅)2)

There total 2 articles about ReH(CO)3((C₆H₅)2PO(CH₂)3OP(C₆H₅)2) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 39.0%

: 870466-08-3
1,3-bis((diphenylphosphino)oxy)propane

: 16457-30-0
hydridopentacarbonylrhenium(I)

: 870466-54-9
mer-[rhenium(I)(hydride)(carbonyl)3(1,3-bis(diphenylphosphinoxy)propane)]

: 870466-54-9
fac-[ReH(CO)3(1,3-bis(diphenylphosphinoxy)propane)]

Guidance literature:: In tetrahydrofuran; toluene; under Ar atm. using Schlenk techniques; soln. of ReH(CO)5 in THF was added to soln. of ligand in toluene; mixt. stirred for 24 h; solid filtered out; monitored by NMR spectroscopy; washed (THF) to remove fac-isomer; leaving mer-isomer washed (EtOH); recrystd. (CH2Cl2/EtOH, 2:10) by slow evapn.; elem. anal.;
DOI:10.1016/j.jorganchem.2005.08.014

Reference yield: 39.0%

: 870466-08-3
1,3-bis((diphenylphosphino)oxy)propane

: 16457-30-0
hydridopentacarbonylrhenium(I)

: 870466-54-9
mer-[rhenium(I)(hydride)(carbonyl)3(1,3-bis(diphenylphosphinoxy)propane)]

: 870466-54-9
fac-[ReH(CO)3(1,3-bis(diphenylphosphinoxy)propane)]

Guidance literature:: In tetrahydrofuran; toluene; under Ar atm. using Schlenk techniques; soln. of ReH(CO)5 in THF was added to soln. of ligand in toluene; mixt. stirred for 24 h; solid filtered out; monitored by NMR spectroscopy; washed (THF) to remove fac-isomer; leaving mer-isomer washed (EtOH); recrystd. (CH2Cl2/EtOH, 2:10) by slow evapn.; elem. anal.;
DOI:10.1016/j.jorganchem.2005.08.014

Reference yield: 80.0%

: 7647-01-0,15364-23-5
hydrogenchloride

: 870466-54-9
mer-[rhenium(I)(hydride)(carbonyl)3(1,3-bis(diphenylphosphinoxy)propane)]

: 1243314-46-6,1243678-98-9
mer, cis-[rhenium(I)(chloride)(carbonyl)3(1,3-bis(diphenylphosphinoxy)propane)]

Guidance literature:: In dichloromethane; byproducts: H2; to suspn. of Re complex (0.2 mmol) cooled to -80°C equimolar amount of HCl (37%) added, mixt. stirred at room temp. for 2 h; ppt. filtered off, recrystd. from CH2Cl2/EtOH by slow evapn. of solvent;elem. anal.;
DOI:10.1002/zaac.200900390