Technology Process of {Fe2(CO)7{μ, η-C(C6H5)C(N(C2H5)2)}}
There total 1 articles about {Fe2(CO)7{μ, η-C(C6H5)C(N(C2H5)2)}} which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
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In
dichloromethane;
react. under dry N2; addn. of ynamine to a suspn. of Fe2(CO)9 in dried CH2Cl2, stirring overnight at room temp. (color change from yellow to dark orange); evapn. (reduced pressure), column chromy. (silica gel), elution with CH2Cl2/hexane (1:10) gives a dark orange band, evapn., recrystn. from n-hexane at -20°C; elem. anal.;
DOI:10.1016/0022-328X(92)80193-2
- Guidance literature:
-
In
hexane;
react. under dry N2; addn. of ynamine to a soln. o Fe-complex in n-hexane, stirring for 6 h at 40°C; evapn., column chromy. (silica gel), elution with n-hexane gives a main yellow band, evapn., recrystn. from n-hexane at -20°C; elem. anal.;
DOI:10.1016/0022-328X(92)80193-2
- Guidance literature:
-
In
hexane;
react. under dry N2; addn. of ynamine to a soln. o Fe-complex in n-hexane, stirring for 6 h at 40°C; evapn., column chromy. (silica gel), elution with n-hexane gives a main yellow band, evapn., recrystn. from n-hexane at -20°C; elem. anal.;
DOI:10.1016/0022-328X(92)80193-2
