trans-(tri(isopropyl) phosphite)(triphenylphosphine)W(CO)4

Base Information

Chemical Name:trans-(tri(isopropyl) phosphite)(triphenylphosphine)W(CO)4
CAS No.:72894-65-6
Molecular Formula:C₃₁H₃₆O₇P₂W
Molecular Weight:766.42
Hs Code.:

Synonyms:

Suppliers and Price of trans-(tri(isopropyl) phosphite)(triphenylphosphine)W(CO)4

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of trans-(tri(isopropyl) phosphite)(triphenylphosphine)W(CO)4

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of trans-(tri(isopropyl) phosphite)(triphenylphosphine)W(CO)4

There total 6 articles about trans-(tri(isopropyl) phosphite)(triphenylphosphine)W(CO)4 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 78.0%

: 60939-03-9
(C₂H₅)4N⁽¹⁺⁾*{(OCH(CH₃)2)3PW(CO)4Cl}^(1-) = (C₂H₅)4N{(OCH(CH₃)2)3PW(CO)4Cl}

: 72894-65-6,72937-34-9
cis-(tri(isopropyl) phosphite)(triphenylphosphine)W(CO)4

Guidance literature:: With triphenylphosphine; In ethanol; (N2); to soln. of phosphine was added W complex and stirred for 2 h at 20°C; to filtered soln. was dropped water and cooled to 0°C, ppt. was filtered off, washed with EtOH/H2O (4/1) and dried in vac.; elem. anal.;
DOI:10.1016/S0022-328X(00)83486-5

Reference yield: 41.0%

: 72894-65-6,72937-34-9
cis-(tri(isopropyl) phosphite)(triphenylphosphine)W(CO)4

: 72894-65-6,72937-34-9
trans-(tri(isopropyl) phosphite)(triphenylphosphine)W(CO)4

Guidance literature:: In methyl cyclohexane; (N2); soln. of W complex was heated at 80°C for 0.5 h, cooled to 0°C and seed crystals of cis-isomer were added; after standing overnight at 0°C cis-isomer was filtered off, from mother liquor crystd. trans-isomer on standing at -20°C for 24 h; recrystn. from CH2Cl2/EtOH; elem. anal.; Kinetics;
DOI:10.1016/S0022-328X(00)83486-5

Reference yield:

: 108795-63-7
cis-{(piperidine)(P(OPr-i)3)W(CO)4}

: 72894-65-6,72937-34-9
cis-(tri(isopropyl) phosphite)(triphenylphosphine)W(CO)4

: 72894-65-6,72937-34-9
trans-(tri(isopropyl) phosphite)(triphenylphosphine)W(CO)4

Guidance literature:: With triphenylphosphine; In chlorobenzene; stirred at 100°C for 24 h; filtered hot, volume reduced, addn. of n-hexane, cooled to 0°C, filtered, recrystn. (toluene/hexane); elem. anal.;
DOI:10.1021/ja00252a014