hexacarbonylbis(μ-1,3-di-p-tolyltriazenido)diruthenium(I/I)

Base Information

• Chemical Name: hexacarbonylbis(μ-1,3-di-p-tolyltriazenido)diruthenium(I/I)
• CAS No.: 743471-52-5
• Molecular Formula: C₃₄H₂₈N₆O₆Ru₂
• Molecular Weight: 818.773
• Mol file: 743471-52-5.mol

Synonyms:

Chemical Property of hexacarbonylbis(μ-1,3-di-p-tolyltriazenido)diruthenium(I/I)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of hexacarbonylbis(μ-1,3-di-p-tolyltriazenido)diruthenium(I/I)

There total 3 articles about hexacarbonylbis(μ-1,3-di-p-tolyltriazenido)diruthenium(I/I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 63.0%

dodecacarbonyl-triangulo-triruthenium (15243-33-1) + 1,3-di(p-tolyl)triaz-1-ene (785-86-4,813445-46-4) → hexacarbonylbis(μ-1,3-di-p-tolyltriazenido)diruthenium(I/I) (114441-48-4,743471-52-5)

Guidance literature:

In acetonitrile; under CO atm., reflux for 5 h; soln. was allowed to stand at 20 °C under CO atm., ppt. was collected, washed with MeCN and EtOH;

DOI:10.1515/znb-2004-0516

Reference yield: 43.5%

catena-{Ru(O2CMe)(CO)2} + 1,3-di(p-tolyl)triaz-1-ene (785-86-4,813445-46-4) → hexacarbonylbis(μ-1,3-di-p-tolyltriazenido)diruthenium(I/I) (114441-48-4,743471-52-5)

Guidance literature:

With CO; triethylamine; In acetonitrile; refluxed in a CO atmosphere for 3 h; allowed to stand under a CO atmosphere for 12 h, filtered, crystn. from CH2Cl2-ethanol, washed with ethanol, dried in vacuo; elem. anal.;

DOI:10.1016/S0277-5387(00)80705-6

Reference yield:

tetracarbonylbis(μ-1,3-di-p-tolyltriazenido)bis(p-toluidine)diruthenium(I/I) (114441-50-8) → hexacarbonylbis(μ-1,3-di-p-tolyltriazenido)diruthenium(I/I) (114441-48-4,743471-52-5)

Guidance literature:

With carbon monoxide; In not given;

DOI:10.1016/S0277-5387(00)80705-6

upstream raw materials:

dodecacarbonyl-triangulo-triruthenium

1,3-di(p-tolyl)triaz-1-ene

tetracarbonylbis(μ-1,3-di-p-tolyltriazenido)bis(p-toluidine)diruthenium(I/I)

Downstream raw materials:

tetracarbonylbis(trimethylphosphite)bis(μ-1,3-di-p-tolyltriazenido)diruthenium(I/I)

{Ru(1,3-di-p-tolyltriazenido)(CO)2(PPh₃)}2