[bis(triphenylphosphine)iminium]2[Ru(CO)3I₃]

Base Information

Chemical Name:[bis(triphenylphosphine)iminium]2[Ru(CO)3I₃]
CAS No.:81432-45-3
Molecular Formula:C₃I₃O₃Ru*C₃₆H₃₀NP₂
Molecular Weight:1104.4
Hs Code.:

[bis(triphenylphosphine)iminium]2[Ru(CO)3I<sub>3</sub>]

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Chemical Property of [bis(triphenylphosphine)iminium]2[Ru(CO)3I₃]

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Technology Process of [bis(triphenylphosphine)iminium]2[Ru(CO)3I₃]

There total 3 articles about [bis(triphenylphosphine)iminium]2[Ru(CO)3I₃] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: bis(triphenylphosphoranylidene)ammonium iodide

: 81432-45-3,81446-81-3,85744-05-4
{PPN}{RuI₃(CO)3}

Guidance literature:: With HI; In tetrahydrofuran; Soln. of Ru-complex and (PPN)I (1:3 mol) in THF treated with HI (57% aq. soln.) dropwise, stirred for 2 h at 25°C, then evapt. to dryness under vac.; residue dissolved in CH2Cl2, diluted with ether, soln. cooled to -35°C for 40 h, product drie under high vac. Elem. anal.;

Reference yield: 82.0%

: [RuI₂(CO)₃]₂

: bis(triphenylphosphoranylidene)ammonium iodide

: 81432-45-3,81446-81-3,85744-05-4
[bis(triphenylphosphine)iminium]2[Ru(CO)3I₃]

Guidance literature:: In tetrahydrofuran; dichloromethane; N2-atmosphere; evapn., recrystn. (MeOH, -25°C); elem. anal.;
DOI:10.1021/om00004a027

Reference yield: 35.0%

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: bis(triphenylphosphoranylidene)ammonium iodide

: (PPN){HRu₃(CO)11}

: 81432-45-3,81446-81-3,85744-05-4
{PPN}{RuI₃(CO)3}

Guidance literature:: With H₂; In tetrahydrofuran; Soln. of Ru3(CO)12 in THF stirred under 30 psig of H2/CO at 65°C, then soln. evapt. to dryness.; Residue extd. with Et2O cooled to -35°C for 17 h, ppt. dried under high vac. Identified by IR;