[(κ2-P,N)-2-(N,N-dimethylaminomethyl)phenyldiphenylphosphino]dimethylplatinum(II)

Base Information

• Chemical Name: [(κ2-P,N)-2-(N,N-dimethylaminomethyl)phenyldiphenylphosphino]dimethylplatinum(II)
• CAS No.: 256422-16-9
• Molecular Formula: C₂₃H₂₈NPPt
• Molecular Weight: 544.536
• Mol file: 256422-16-9.mol

Synonyms:

Chemical Property of [(κ2-P,N)-2-(N,N-dimethylaminomethyl)phenyldiphenylphosphino]dimethylplatinum(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [(κ2-P,N)-2-(N,N-dimethylaminomethyl)phenyldiphenylphosphino]dimethylplatinum(II)

There total 1 articles about [(κ2-P,N)-2-(N,N-dimethylaminomethyl)phenyldiphenylphosphino]dimethylplatinum(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 81.0%

(norbornadiene)dimethylplatinum(II) (53199-36-3) + [2-(N,N-dimethylaminomethyl)phenyl]diphenylphosphane (53881-33-7) → [(κ2-P,N)-2-(N,N-dimethylaminomethyl)phenyldiphenylphosphino]dimethylplatinum(II) (256422-16-9)

Guidance literature:

In benzene; under Ar atm. to stirred soln. (nbd)PtMe2 in benzene (2-diphenylphosphinobenzyl)dimethylamine in benzene was added dropwise, soln. was stirred for 2 h; soln. was concd. under reduced pressure and diluted with petroleum ether, react. mixt. was stored at -30°C for 24 h, ppt. was filtered off, washed with petroleum ether and dried under reduced pressure; elem. anal.;

DOI:10.1021/om990665d

Reference yield: 82.0%

trimethylsilyl iodide (16029-98-4) + [(κ2-P,N)-2-(N,N-dimethylaminomethyl)phenyldiphenylphosphino]dimethylplatinum(II) (256422-16-9) → trans-[(κ2-P,N)-2-(N,N-dimethylaminomethyl)phenyldiphenylphosphino](iodo)methylplatinum(II) (256422-24-9)

Guidance literature:

In benzene; under Ar atm. platinum dimethyl complex and iodotrimethylsilane in benzene were stirred for 12 h at 60°C; react. mixt. was poured into petroleum ether and stored for 24 h at -30°C, ppt. was filtered off, washed with petroleum ether, and driedunder reduced pressure; elem. anal.;

DOI:10.1021/om990665d

Reference yield: 77.0%

[(κ2-P,N)-2-(N,N-dimethylaminomethyl)phenyldiphenylphosphino]dimethylplatinum(II) (256422-16-9) + 1,2-bis(dimethylsilyl)benzene (17985-72-7) → [(κ2-P,N)-2-(N,N-dimethylaminomethyl)phenyldiphenylphosphino][1,2-bis(dimethylsilyl)benzene]platinum(II) (256422-27-2)

Guidance literature:

In benzene; under Ar atm. to soln. dimethylplatinum(II) complex in benzene 1,2-bis(dimethylsilyl)benzene was added dropwise, react. mixt. was stirred for 60 h at 60°C; soln. was cooled to room temp., transferred into petroleum ether and stored at -30°C for 24 h, ppt. was filtered off, washed with petroleum ether, and dried under reduced pressure; elem. anal.;

DOI:10.1021/om990665d

upstream raw materials:

(norbornadiene)dimethylplatinum(II)

[2-(N,N-dimethylaminomethyl)phenyl]diphenylphosphane

Downstream raw materials:

[(κ2-P,N)-2-(N,N-dimethylaminomethyl)phenyldiphenylphosphino][1,2-bis(dimethylsilyl)benzene]platinum(II)

trans-[(κ2-P,N)-2-(N,N-dimethylaminomethyl)phenyldiphenylphosphino](iodo)methylplatinum(II)