1-(2-(Diphenylphosphanyl)phenyl)-N,N-dimethylmethanamine

Base Information

Chemical Name:1-(2-(Diphenylphosphanyl)phenyl)-N,N-dimethylmethanamine
CAS No.:53881-33-7
Molecular Formula:C₂₁H₂₂NP
Molecular Weight:319.386
Hs Code.:
European Community (EC) Number:803-965-3
Nikkaji Number:J1.062.039B
Mol file:53881-33-7.mol

Synonyms:53881-33-7;1-(2-(Diphenylphosphanyl)phenyl)-N,N-dimethylmethanamine;starbld0006425;(2-((Dimethylamino)methyl)phenyl)diphenylphosphine;SCHEMBL3665712;POILNYUNIDNVDD-UHFFFAOYSA-N;2-(diphenylphosphino)-N,N-dimethylbenzenemethanamine;2-(Diphenylphosphino)-N,N-dimethylbenzylamine, 95%;1-(2-diphenylphosphanylphenyl)-N,N-dimethylmethanamine;N,N-dimethyl-[2-(diphenyl-phosphino)phenyl]methaneamine

Suppliers and Price of 1-(2-(Diphenylphosphanyl)phenyl)-N,N-dimethylmethanamine

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
2-(Diphenylphosphino)-N,N-dimethylbenzylamine 95%
5g
$ 316.00

Total 2 raw suppliers

Chemical Property of 1-(2-(Diphenylphosphanyl)phenyl)-N,N-dimethylmethanamine

Chemical Property:

Melting Point:55-59°C
XLogP3:4.4
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:1
Rotatable Bond Count:5
Exact Mass:319.148986704
Heavy Atom Count:23
Complexity:313

Purity/Quality:

98%,99%, ^*data from raw suppliers

2-(Diphenylphosphino)-N,N-dimethylbenzylamine 95% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xn
Statements: 22-36/37/38
Safety Statements: 26-36/37/39

MSDS Files:

Useful:

Canonical SMILES:CN(C)CC1=CC=CC=C1P(C2=CC=CC=C2)C3=CC=CC=C3
Uses Phosphine ligand for cross coupling

Technology Process of 1-(2-(Diphenylphosphanyl)phenyl)-N,N-dimethylmethanamine

There total 11 articles about 1-(2-(Diphenylphosphanyl)phenyl)-N,N-dimethylmethanamine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

: di-μ-chlorobis-[[2-(dimethylamino)methyl]phenyl-C,N]dipalladium(II)

: 829-85-6
diphenylphosphane

: 53881-33-7
[2-(N,N-dimethylaminomethyl)phenyl]diphenylphosphane

Guidance literature:: With caesium carbonate; In toluene; at 40 ℃; for 18h; Solvent; Time; Temperature; Inert atmosphere; Schlenk technique;
DOI:10.1016/j.jorganchem.2016.12.023

Reference yield: 58.0%

: bis[(benzyldimethylamino)chloropalladium(II)]

: 15475-27-1,4346-39-8
potassium diphenylphosphine

: 53881-33-7
[2-(N,N-dimethylaminomethyl)phenyl]diphenylphosphane

Guidance literature:: In tetrahydrofuran; at 20 ℃; for 18h; chemoselective reaction; Inert atmosphere;
DOI:10.1016/j.jorganchem.2010.10.020

Reference yield: 47.0%

: 97106-61-1
diphenyl(2-(trimethylstannyl)phenyl)phosphane

: 30354-18-8
N,N-dimethyl(methylene)ammonium chloride

: 53881-33-7
[2-(N,N-dimethylaminomethyl)phenyl]diphenylphosphane

Guidance literature:: diphenyl(2-(trimethylstannyl)phenyl)phosphane; With methyllithium; In tetrahydrofuran; diethyl ether; at -78 - 20 ℃; for 0.5h; Schlenk technique; Inert atmosphere;

N,N-dimethyl(methylene)ammonium chloride; In tetrahydrofuran; diethyl ether; at -78 - 20 ℃; for 4h; Schlenk technique; Inert atmosphere;
DOI:10.1002/anie.201509329