Pd(P(C₆H₅)2C₂H₄P(C₆H₅)2)(⁽¹³⁾CH₃)PH(C₆H₂(CH₃)3)2⁽¹⁺⁾*CF₃SO₃^(1-)=Pd(P(C₆H₅)2C₂H₄P(C₆H₅)2)⁽¹³⁾CH₃PH(C₆H₂(CH₃)3)2(CF₃SO₃)

Base Information

• Chemical Name: Pd(P(C₆H₅)2C₂H₄P(C₆H₅)2)(⁽¹³⁾CH₃)PH(C₆H₂(CH₃)3)2⁽¹⁺⁾*CF₃SO₃^(1-)=Pd(P(C₆H₅)2C₂H₄P(C₆H₅)2)⁽¹³⁾CH₃PH(C₆H₂(CH₃)3)2(CF₃SO₃)
• CAS No.: 287945-34-0
• Molecular Formula: CF₃O₃S*C₄₅H₅₀P₃Pd
• Molecular Weight: 940.293
• Mol file: 287945-34-0.mol

Synonyms:

Chemical Property of Pd(P(C₆H₅)2C₂H₄P(C₆H₅)2)(⁽¹³⁾CH₃)PH(C₆H₂(CH₃)3)2⁽¹⁺⁾*CF₃SO₃^(1-)=Pd(P(C₆H₅)2C₂H₄P(C₆H₅)2)⁽¹³⁾CH₃PH(C₆H₂(CH₃)3)2(CF₃SO₃)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Pd(P(C₆H₅)2C₂H₄P(C₆H₅)2)(⁽¹³⁾CH₃)PH(C₆H₂(CH₃)3)2⁽¹⁺⁾*CF₃SO₃^(1-)=Pd(P(C₆H₅)2C₂H₄P(C₆H₅)2)⁽¹³⁾CH₃PH(C₆H₂(CH₃)3)2(CF₃SO₃)

There total 3 articles about Pd(P(C₆H₅)2C₂H₄P(C₆H₅)2)(⁽¹³⁾CH₃)PH(C₆H₂(CH₃)3)2⁽¹⁺⁾*CF₃SO₃^(1-)=Pd(P(C₆H₅)2C₂H₄P(C₆H₅)2)⁽¹³⁾CH₃PH(C₆H₂(CH₃)3)2(CF₃SO₃) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

PdP(C6H5)2C2H4P(C6H5)2PH(C6H2(CH3)3)2Cl(1+)*O3SCF3(1-)=PdP2(C6H5)4C2H4PH(C6H2(CH3)3)2Cl(SO3CF3) (287945-30-6) → Pd(P(C6H5)2C2H4P(C6H5)2)((13)CH3)PH(C6H2(CH3)3)2(1+)*CF3SO3(1-)=Pd(P(C6H5)2C2H4P(C6H5)2)(13)CH3PH(C6H2(CH3)3)2(CF3SO3) (287945-34-0)

Guidance literature:

Multi-step reaction with 2 steps

1: acetone

2: acetonitrile; tetrahydrofuran

In tetrahydrofuran; acetone; acetonitrile;

DOI:10.1021/om000164o

Reference yield:

Pd(C6H5CHCHCOCHCOCHCHC6H5)(P(C6H5)2C2H4P(C6H5)2) → Pd(P(C6H5)2C2H4P(C6H5)2)((13)CH3)PH(C6H2(CH3)3)2(1+)*CF3SO3(1-)=Pd(P(C6H5)2C2H4P(C6H5)2)(13)CH3PH(C6H2(CH3)3)2(CF3SO3) (287945-34-0)

Guidance literature:

Multi-step reaction with 2 steps

1: not given

2: acetonitrile; tetrahydrofuran

In tetrahydrofuran; acetonitrile;

DOI:10.1021/om000164o

Reference yield:

Pd(P(C6H5)2C2H4P(C6H5)2)(13)CH3I + dimesityl phosphine (1732-66-7) + silver trifluoromethanesulfonate (2923-28-6) → Pd(P(C6H5)2C2H4P(C6H5)2)((13)CH3)PH(C6H2(CH3)3)2(1+)*CF3SO3(1-)=Pd(P(C6H5)2C2H4P(C6H5)2)(13)CH3PH(C6H2(CH3)3)2(CF3SO3) (287945-34-0)

Guidance literature:

In tetrahydrofuran; acetonitrile; byproducts: AgCl; PHMes2 and AgOTf were added to a stirred suspn. of complex in THF and CH3CN, protected from light, stirred fo 60 min at 20°C under N2; filtered, reduced in vol., petroleum ether was added, cooled to -25°C;

DOI:10.1021/om000164o

upstream raw materials:

dimesityl phosphine

silver trifluoromethanesulfonate

PdP(C₆H₅)2C₂H₄P(C₆H₅)2PH(C₆H₂(CH₃)3)2Cl⁽¹⁺⁾*O₃SCF₃^(1-)=PdP₂(C₆H₅)4C₂H₄PH(C₆H₂(CH₃)3)2Cl(SO₃CF₃)