C₆₉H₇₀⁽²⁾H₂N₆O₉Si

Base Information

• Chemical Name: C₆₉H₇₀⁽²⁾H₂N₆O₉Si
• CAS No.: 1373889-15-6
• Molecular Formula: C₆₉H₇₂N₆O₉Si
• Molecular Weight: 1159.44
• Mol file: 1373889-15-6.mol

Synonyms:

Chemical Property of C₆₉H₇₀⁽²⁾H₂N₆O₉Si

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of C₆₉H₇₀⁽²⁾H₂N₆O₉Si

There total 12 articles about C₆₉H₇₀⁽²⁾H₂N₆O₉Si which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

C62H66(2)H2N6O8Si (1373889-13-4) + benzoyl chloride (98-88-4) → C69H70(2)H2N6O9Si (1373889-15-6)

Guidance literature:

With dmap; triethylamine; In dichloromethane; at 20 ℃; for 5h;

DOI:10.1021/ja302711z

Reference yield:

dibenzylamine (103-49-1) → C69H70(2)H2N6O9Si (1373889-15-6)

Guidance literature:

Multi-step reaction with 6 steps

1: benzotriazol-1-ol; O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate; N-ethyl-N,N-diisopropylamine / N,N-dimethyl-formamide / 12 h / 0 - 20 °C / Inert atmosphere

2: lithium hydroxide / tetrahydrofuran; water / 1 h

3: benzotriazol-1-ol; O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate; N-ethyl-N,N-diisopropylamine / N,N-dimethyl-formamide / 12 h / 0 - 20 °C / Inert atmosphere

4: trifluoroacetic acid / dichloromethane / 16 h

5: benzotriazol-1-ol; O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate; N-ethyl-N,N-diisopropylamine / N,N-dimethyl-formamide / 16 h / 0 - 20 °C / Inert atmosphere

6: dmap; triethylamine / dichloromethane / 5 h / 20 °C

With dmap; benzotriazol-1-ol; O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate; triethylamine; N-ethyl-N,N-diisopropylamine; trifluoroacetic acid; lithium hydroxide; In tetrahydrofuran; dichloromethane; water; N,N-dimethyl-formamide;

DOI:10.1021/ja302711z

Reference yield:

C18H15(2)H2NO3 (1373889-06-5) → C69H70(2)H2N6O9Si (1373889-15-6)

Guidance literature:

Multi-step reaction with 5 steps

1: benzotriazol-1-ol; O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate; N-ethyl-N,N-diisopropylamine / N,N-dimethyl-formamide / 16 h / 0 - 20 °C / Inert atmosphere

2: tetrabutyl ammonium fluoride / tetrahydrofuran / 18 h

3: lithium hydroxide / tetrahydrofuran; water / 0.42 h

4: benzotriazol-1-ol; O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate; N-ethyl-N,N-diisopropylamine / N,N-dimethyl-formamide / 16 h / 0 - 20 °C / Inert atmosphere

5: dmap; triethylamine / dichloromethane / 5 h / 20 °C

With dmap; tetrabutyl ammonium fluoride; benzotriazol-1-ol; O-(benzotriazol-1-yl)-N,N,N',N'-tetramethyluronium tetrafluoroborate; triethylamine; N-ethyl-N,N-diisopropylamine; lithium hydroxide; In tetrahydrofuran; dichloromethane; water; N,N-dimethyl-formamide;

DOI:10.1021/ja302711z

upstream raw materials:

(E)-4-(dibenzylamino)-4-oxobut-2-enoic acid

C₁₉H₁₇⁽²⁾H₂NO₃

C₁₈H₁₅⁽²⁾H₂NO₃

C₃₀H₄₂N₂O₆Si

Downstream raw materials:

C₅₃H₅₂⁽²⁾H₂N₆O₉