9β-hydroxy-9,10-secocholesta-1,3,5(10)-triene

Base Information

Chemical Name:9β-hydroxy-9,10-secocholesta-1,3,5(10)-triene
CAS No.:75415-47-3
Molecular Formula:C₂₇H₄₄O
Molecular Weight:384.646
Hs Code.:

Synonyms:

Suppliers and Price of 9β-hydroxy-9,10-secocholesta-1,3,5(10)-triene

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of 9β-hydroxy-9,10-secocholesta-1,3,5(10)-triene

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of 9β-hydroxy-9,10-secocholesta-1,3,5(10)-triene

There total 24 articles about 9β-hydroxy-9,10-secocholesta-1,3,5(10)-triene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 26358-65-6
5α-cholestane-3β,6β-diol 6-acetate

: 75415-47-3,75415-48-4
9α-hydroxy-9,10-secocholesta-1,3,5(10)-triene

Guidance literature:: Multi-step reaction with 10 steps

1: 22 g / triphenylphosphine, diethyl azodicarboxylate / tetrahydrofuran / 15 h

2: 2.) KOH / 1.) chlorination, 2.) H₂O, EtOH

3: 11 g / pyridine / 16 h / 25 °C

4: 5.9 g / phosphoryl chloride, pyridine / 20 h / 20 °C

5: 3.2 g / KOH / methanol; benzene / 12 h / 20 °C

6: Jones reagent / acetone / 0.17 h

7: H₂SO₄ / acetone / 16 h

8: 500 mg / dichlorodicyanobenzoquinone / benzene / 24 h / Heating

9: 90 percent / m-chloroperbenzoic acid / CH₂Cl₂

10: 190 mg / LiAlH₄ / tetrahydrofuran / 16 h / Heating

With pyridine; potassium hydroxide; lithium aluminium tetrahydride; jones reagent; sulfuric acid; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; diethylazodicarboxylate; trichlorophosphate; In tetrahydrofuran; methanol; dichloromethane; acetone; benzene;

Reference yield:

: 26358-65-6
5α-cholestane-3β,6β-diol 6-acetate

: 75415-47-3,75415-48-4
9β-hydroxy-9,10-secocholesta-1,3,5(10)-triene

Guidance literature:: Multi-step reaction with 10 steps

1: 22 g / triphenylphosphine, diethyl azodicarboxylate / tetrahydrofuran / 15 h

2: 2.) KOH / 1.) chlorination, 2.) H₂O, EtOH

3: 11 g / pyridine / 16 h / 25 °C

4: 5.9 g / phosphoryl chloride, pyridine / 20 h / 20 °C

5: 3.2 g / KOH / methanol; benzene / 12 h / 20 °C

6: Jones reagent / acetone / 0.17 h

7: H₂SO₄ / acetone / 16 h

8: 500 mg / dichlorodicyanobenzoquinone / benzene / 24 h / Heating

9: 90 percent / m-chloroperbenzoic acid / CH₂Cl₂

10: 300 mg / LiAlH₄ / tetrahydrofuran / 16 h / Heating

With pyridine; potassium hydroxide; lithium aluminium tetrahydride; jones reagent; sulfuric acid; 3-chloro-benzenecarboperoxoic acid; triphenylphosphine; 2,3-dicyano-5,6-dichloro-p-benzoquinone; diethylazodicarboxylate; trichlorophosphate; In tetrahydrofuran; methanol; dichloromethane; acetone; benzene;

Reference yield:

: 37772-32-0
cholest-9(11)-en-3α-ol

: 75415-47-3,75415-48-4
9α-hydroxy-9,10-secocholesta-1,3,5(10)-triene

Guidance literature:: Multi-step reaction with 5 steps

1: 97 percent / Jones reagent / acetone

2: 150 mg / pyridinium hydrobromide perbromide / tetrahydrofuran / 1.) 0 deg C, 15 min, 2.) 20 deg C, 30 min

3: 127 mg / LiBr, Li₂CO₃ / dimethylformamide / 2 h / 135 °C

4: 90 percent / m-chloroperbenzoic acid / CH₂Cl₂

5: 190 mg / LiAlH₄ / tetrahydrofuran / 16 h / Heating

With lithium aluminium tetrahydride; jones reagent; pyridinium hydrobromide perbromide; lithium carbonate; 3-chloro-benzenecarboperoxoic acid; lithium bromide; In tetrahydrofuran; dichloromethane; N,N-dimethyl-formamide; acetone;