bis(2-phenylpropyl)[1,2-bis(diphenylphosphanyl)ethane]palladium

Base Information

Chemical Name:bis(2-phenylpropyl)[1,2-bis(diphenylphosphanyl)ethane]palladium
CAS No.:500128-40-5
Molecular Formula:C₄₄H₄₆P₂Pd
Molecular Weight:743.217
Hs Code.:

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of bis(2-phenylpropyl)[1,2-bis(diphenylphosphanyl)ethane]palladium

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Technology Process of bis(2-phenylpropyl)[1,2-bis(diphenylphosphanyl)ethane]palladium

There total 1 articles about bis(2-phenylpropyl)[1,2-bis(diphenylphosphanyl)ethane]palladium which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 19978-61-1
(1,2-bis(diphenylphosphanyl)ethane)dichloridopalladium(II)

: 64740-49-4
(2-phenylpropyl)lithium

: 500128-40-5,500295-66-9
bis(2-phenylpropyl)[1,2-bis(diphenylphosphanyl)ethane]palladium

Guidance literature:: In toluene; byproducts: LiCl; soln. of LiCH2CHCH3C6H5 in toluene added to PdCl2(dppe) complex at -78°C under Ar, warmed to -30°C, stirred overnight; filtered soln. concentrated at -30°C in vacuum, cooled to -78°C, added n-pentane, precipitate filtered, washed with n-pentane, dried at -30°C in vacuum;
DOI:10.1002/1099-0682(200211)2002:11<2868::AID-EJIC2868>3.0.CO;2-S

Reference yield: 74.0%

: 500128-40-5,500295-66-9
bis(2-phenylpropyl)[1,2-bis(diphenylphosphanyl)ethane]palladium

: 108-98-5
thiophenol

: 33971-07-2
{1,2-bis(diphenylphosphino)ethane}di(phenylthio)palladium(II)

: 500128-43-8
(2-phenylpropyl)(SC₆H₅)[1,2-bis(diphenylphosphanyl)ethane]palladium

Guidance literature:: In tetrahydrofuran; byproducts: (CH3)2CHC6H5; to soln. of Pd(CH2CHCH3C6H5)2(dppe) in THF added C6H5SH (1:1 molar ratio) at -78°C under Ar, warmed to -30°C, stirred overnight; further C6H5SH added (final molar ratio 6:1) at -30°C until Pd complex reacted; THF removed at -30°C in vacuum, taken up in toluene, at -78°C pentane added, precipitate filtered, washed with pentane, dried at -30°C in vacuum;
DOI:10.1002/1099-0682(200211)2002:11<2868::AID-EJIC2868>3.0.CO;2-S