[Cr₂(acetato)2(N,N'-bis(2,6-xylyl)formamidinate)2(THF)2]

Base Information

• Chemical Name: [Cr₂(acetato)2(N,N'-bis(2,6-xylyl)formamidinate)2(THF)2]
• CAS No.: 292143-00-1
• Molecular Formula: C₄₆H₆₀Cr₂N₄O₆
• Molecular Weight: 868.998
• Mol file: 292143-00-1.mol

Synonyms:

Chemical Property of [Cr₂(acetato)2(N,N'-bis(2,6-xylyl)formamidinate)2(THF)2]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Cr₂(acetato)2(N,N'-bis(2,6-xylyl)formamidinate)2(THF)2]

There total 2 articles about [Cr₂(acetato)2(N,N'-bis(2,6-xylyl)formamidinate)2(THF)2] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

N,N'-bis-2,6-xylylformamidine (16596-05-7) + chromium(II) acetate (628-52-4,17593-70-3) → [Cr2(acetato)2(N,N'-bis(2,6-xylyl)formamidinate)2(THF)2] (292143-00-1)

Guidance literature:

With CH₃Li; THF; In tetrahydrofuran; diethyl ether; byproducts: LiCl; MeLi in Et2O was added dropwise to a suspn. of ligand in THF, then addedto a suspn. anhyd. CrAc2 in THF, 4 h (N2 atm.); THF was removed in vac., washed with ice-cold hexane, ppt. was dissoved in benzene, filtered, evapd.;

DOI:10.1039/b000326n

Reference yield: 41.0%

[Cr2(N,N'-bis(2,6-xylyl)formamidinate)2(μ-Cl)2(THF)2] (292142-99-5) + sodium acetate (127-09-3) → [Cr2(acetato)2(N,N'-bis(2,6-xylyl)formamidinate)2(THF)2] (292143-00-1)

Guidance literature:

In tetrahydrofuran; byproducts: LiCl; anhyd. NaAc in THF was added dropwise to a soln. of complex in THF, 4 h (N2 atm.); THF was removed in vac., ppt. was dissoved in benzene, filtered, evapd.;elem. anal.;

DOI:10.1039/b000326n

upstream raw materials:

N,N'-bis-2,6-xylylformamidine

chromium(II) acetate

[Cr2(N,N'-bis(2,6-xylyl)formamidinate)2(μ-Cl)2(THF)2]

sodium acetate