(C₅H₅)Fe(C₅H₄CHCHC₆H₄C₄H₅(CH₃)2O₂)

Base Information

• Chemical Name: (C₅H₅)Fe(C₅H₄CHCHC₆H₄C₄H₅(CH₃)2O₂)
• CAS No.: 877307-36-3
• Molecular Formula: C₂₄H₂₆FeO₂
• Molecular Weight: 402.316
• Mol file: 877307-36-3.mol

Synonyms:

Chemical Property of (C₅H₅)Fe(C₅H₄CHCHC₆H₄C₄H₅(CH₃)2O₂)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (C₅H₅)Fe(C₅H₄CHCHC₆H₄C₄H₅(CH₃)2O₂)

There total 1 articles about (C₅H₅)Fe(C₅H₄CHCHC₆H₄C₄H₅(CH₃)2O₂) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 96.0%

ferrocenecarboxaldehyde (12093-10-6) + (4-(5,5-dimethyl-[1,3]-dioxan-2-yl)benzyl)phosphonic aciddiethyl ester (404822-87-3) → (C5H5)Fe(C5H4CHCHC6H4C4H5(CH3)2O2) (877307-36-3,877459-62-6)

Guidance literature:

With potassium tert-butylate; In tetrahydrofuran; t-C4H9OK was added to a degassed soln. of ferrocene-compound and phosphonate in dry THF at 0°C under Ar, the mixt. was stirred for 2 h; filtered, evapd. to dryness, taken up in CH2Cl2, the organic layer was washed with H2O, dried over MgSO4, filtered and evapd. to dryness, columnchromy. (silica gel, hexane/CH2Cl2 3:2); elem. anal.;

DOI:10.1039/b711030h

Reference yield: 80.0%

(C5H5)Fe(C5H4CHCHC6H4C4H5(CH3)2O2) (877307-36-3,877459-62-6) + trifluoroacetic acid (76-05-1) → 4‐(2‐ferrocenylvinyl)benzaldehyde (123931-08-8,72022-45-8,98243-45-9)

Guidance literature:

With water; In dichloromethane; a 1:1 mixt. of CF3CO2H/H2O was added to a degassed soln. of complex in CH2Cl2 under Ar, the mixt. was stirred at room temp. for 5 h under Ar; washed with H2O, (until pH was neat neutrality), dried over MgSO4, filtered, evapd. to dryness, column chromy. (silica gel, CH2Cl2/hexane 1:1); elem. anal.;

DOI:10.1039/b711030h

Reference yield: 70.0%

(C5H5)Fe(C5H4CHCHC6H4C4H5(CH3)2O2) (877307-36-3,877459-62-6) + trifluoroacetic acid (76-05-1) → (C5H5)Fe(C5H4CHCHC6H4C2H2C6H4CHO) (300710-65-0,329246-78-8)

Guidance literature:

With water; In dichloromethane; a 1:1 mixt. of CF3CO2H/H2O was added to a degassed soln. of complex in CH2Cl2 under Ar, the mixt. was stirred at room temp. for 5 h under Ar; washed with H2O, (until pH was neat neutrality), dried over MgSO4, filtered, evapd. to dryness, column chromy. (silica gel, CH2Cl2/hexane 1:1); elem. anal.;

DOI:10.1039/b711030h

upstream raw materials:

ferrocenecarboxaldehyde

(4-(5,5-dimethyl-[1,3]-dioxan-2-yl)benzyl)phosphonic aciddiethyl ester

Downstream raw materials:

4‐(2‐ferrocenylvinyl)benzaldehyde

(C₅H₅)Fe(C₅H₄CHCHC₆H₄C₂H₂C₆H₄CHO)