fac-[Mn(CCCO₂Me)(dppm)]

Base Information

Chemical Name:fac-[Mn(CCCO₂Me)(dppm)]
CAS No.:852615-37-3
Molecular Formula:C₃₂H₂₅MnO₅P₂
Molecular Weight:606.433
Hs Code.:

Synonyms:

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Chemical Property of fac-[Mn(CCCO₂Me)(dppm)]

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Technology Process of fac-[Mn(CCCO₂Me)(dppm)]

There total 1 articles about fac-[Mn(CCCO₂Me)(dppm)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 30.0%

: {Mn(CO)4((Ph₂P)2CH)}

: 922-67-8
propynoic acid methyl ester

: Mn(CO)4((C₆H₅)2PC(CHCHCOOCH₃)P(C₆H₅)2)

: 852615-37-3
fac-[Mn(CCCO₂Me)(dppm)]

Guidance literature:: In toluene; byproducts: CO; under N2; soln. of Mn complex and HCCCO2Me (molar ratio 1:5) in toluene stirred at reflux for 5 h; solvent evapd. to dryness; sepd. by column chromy. (alumina, CH2Cl2-hexane 1:1); elem. anal.;
DOI:10.1021/om050146c

Reference yield: 90.0%

: tetrafluoroboric acid - diethyl ether

: 852615-37-3
fac-[Mn(CCCO₂Me)(dppm)]

: 852615-39-5
Mn(CO)3((C₆H₅)2PCH₂P(C₆H₅)2CCHC(OCH₃)O)⁽¹⁺⁾*BF₄^(1-)=(Mn(CO)3((C₆H₅)2PCH₂P(C₆H₅)2CCHC(OCH₃)O))BF₄

Guidance literature:: In diethyl ether; dichloromethane; under N2; Et2O soln. of HBF4*99Et2O (1.3 equiv.) added to soln. of Mn complex in CH2Cl2 with stirring; solvent evapd.; oil washed with Et2O; recrystd. from CH2Cl2-hexane; elem. anal.;
DOI:10.1021/om050146c

Reference yield:

: tetrafluoroboric acid - diethyl ether

: 852615-37-3
fac-[Mn(CCCO₂Me)(dppm)]

: fac-[Mn(C=C(H)CO₂Me)(CO)3(dppm)]BF₄

Guidance literature:: In diethyl ether; dichloromethane-d2; under N2; in NMR tube; Et2O soln. of HBF4*99Et2O (3.3 equiv.) added to soln. of Mn complex in CD2Cl2 at 200 K; not isolated; detd. by (1)H and (31)P NMR spectra;
DOI:10.1021/om050146c