C₆₀H₉₂O₅PS₂⁽¹⁺⁾*Br^(1-)

Base Information

• Chemical Name: C₆₀H₉₂O₅PS₂⁽¹⁺⁾*Br^(1-)
• CAS No.: 1454275-77-4
• Molecular Formula: Br*C₆₀H₉₂O₅PS₂
• Molecular Weight: 1068.4
• Mol file: 1454275-77-4.mol

Synonyms:

Chemical Property of C₆₀H₉₂O₅PS₂⁽¹⁺⁾*Br^(1-)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
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MSDS Files:

Useful:

Technology Process of C₆₀H₉₂O₅PS₂⁽¹⁺⁾*Br^(1-)

There total 4 articles about C₆₀H₉₂O₅PS₂⁽¹⁺⁾*Br^(1-) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

1-(bromomethyl)-3,4,5-tris(dodecyloxy)-benzene (478083-71-5) + C17H13O2PS2 (1454275-76-3) → C60H92O5PS2(1+)*Br(1-) (1454275-77-4)

Guidance literature:

In tetrahydrofuran; toluene; Reflux; Inert atmosphere; Schlenk technique;

DOI:10.1002/anie.201303729

Reference yield:

bis(3-bromothiophen-2-yl)methanol → C60H92O5PS2(1+)*Br(1-) (1454275-77-4)

Guidance literature:

Multi-step reaction with 4 steps

1.1: pyridinium chlorochromate / dichloromethane / 0 - 20 °C / Inert atmosphere; Schlenk technique; Molecular sieve

2.1: toluene-4-sulfonic acid / benzene / 60 h / Inert atmosphere; Schlenk technique; Dean-Stark; Reflux

3.1: n-butyllithium / diethyl ether; tetrahydrofuran / 1 h / -78 - 20 °C / Inert atmosphere; Schlenk technique

3.2: -78 °C / Inert atmosphere; Schlenk technique

4.1: tetrahydrofuran; toluene / Reflux; Inert atmosphere; Schlenk technique

With n-butyllithium; toluene-4-sulfonic acid; pyridinium chlorochromate; In tetrahydrofuran; diethyl ether; dichloromethane; toluene; benzene;

DOI:10.1002/anie.201303729

Reference yield:

2,2-bis (3-bromo-2-thienyl) -1,3-dioxolane (1454275-81-0) → C60H92O5PS2(1+)*Br(1-) (1454275-77-4)

Guidance literature:

Multi-step reaction with 2 steps

1.1: n-butyllithium / diethyl ether; tetrahydrofuran / 1 h / -78 - 20 °C / Inert atmosphere; Schlenk technique

1.2: -78 °C / Inert atmosphere; Schlenk technique

2.1: tetrahydrofuran; toluene / Reflux; Inert atmosphere; Schlenk technique

With n-butyllithium; In tetrahydrofuran; diethyl ether; toluene;

DOI:10.1002/anie.201303729

upstream raw materials:

1-(bromomethyl)-3,4,5-tris(dodecyloxy)-benzene

C₁₇H₁₃O₂PS₂

bis(3-bromothiophen-2-yl)methanone

2,2-bis (3-bromo-2-thienyl) -1,3-dioxolane

Downstream raw materials:

C₅₈H₈₈O₄PS₂⁽¹⁺⁾*Br^(1-)