478083-71-5

Upstream product

• 138433-00-8 3,4,5-tris(dodecyloxy)benzyl alcohol 
• 2857-97-8 trimethylsilyl bromide 
• 149-91-7 3,4,5-trihydroxybenzoic acid 
• 117241-30-2 ethyl 3,4,5-tri(dodecyloxy)benzoate 
• 831-61-8 Ethyl gallate 
• 123126-39-6 methyl [3,4,5-tris(n-dodecan-1-yloxy)]benzoate 
• 143-15-7 1-dodecylbromide 
• 99-24-1 methyl galloate 

Downstream Products

• 253598-65-1 (3,4,5-tris-dodecyloxy-benzyl)-phosphonic acid diethyl ester 
• 1334702-23-6 CF₃O₃S^(1-)*C₅₇H₈₈O₃PS₂⁽¹⁺⁾ 
• 1334702-18-9 P-phenyl-di(benzothieno)phosphole 
• 1334702-17-8 Br^(1-)*C₆₃H₉₂O₃PS⁽¹⁺⁾ 
• 1379747-56-4 CF₃O₃S^(1-)*C₆₉H₉₆O₃PS₂⁽¹⁺⁾ 
• 1379747-58-6 Br^(1-)*C₆₅H₉₂O₃PS₄⁽¹⁺⁾ 
• 1379747-63-3 Br^(1-)*C₈₁H₁₀₄O₃PS₂⁽¹⁺⁾ 
• 1361243-32-4 4-{[3,4,5-tris(dodecyloxy)benzyl]oxy}benzaldehyde 

Relevant academic research and scientific papers

Dendritic host molecules with a polycationic core and an outer shell of dodecyl groups

The synthesis of a topologically new type of dendrimer is presented in which a permanently positively charged core is decorated with a shell that is apolar and aliphatic in nature. The novel polyionic dendrimers were successfully applied as hosts for a pr

Self-assembly of taper- and wedge-shaped maleimide derivatives: Synthesis and structure-property relationship

Herein, we describe design and synthesis of five new amphiphilic systems, viz. 10b-c and 11a-c composed of maleimide at the focal point and alkoxy phenyl ring at the periphery. Their self-assembling behaviour was examined systematically by varying the length of hydrophobic part and aromatic core segment. Evidently, on increasing the aromatic core length, maleimide based amphiphiles relatively emerge as two distinct molecular structures, i.e. wedge- and tapered-shaped. The mesomorphic studies of the two series reveal that, tapered-shaped maleimide derivatives assemble into a smectic A phase with an interesting phasmidic arrangement, whereas the wedge-shaped molecules exclusively form a prospective supramolecular hexagonal columnar mesophase through the intermolecular hydrogen-bonding via maleimide head group. These self-assembled materials could demonstrate high-sensitivity towards various external stimuli.

Dicyanamide Salts that Adopt Smectic, Columnar, or Bicontinuous Cubic Liquid-Crystalline Mesophases

Although dicyanamide (i.e., [N(CN)2]?) has been commonly used to obtain low-viscosity, halogen-free, room-temperature ionic liquids, liquid-crystalline salts containing such anions have remained virtually unexplored. Here we report a

Wide-Range Columnar and Lamellar Photoluminescent Liquid-Crystalline Lanthanide Complexes with Mesogenic 4-Pyridone Derivatives

A series of liquid crystals with various lanthanide ions (EuIII, SmIII, and TbIII) was designed and prepared starting from the corresponding lanthanide nitrates and N-alkylated 4-pyridone derivatives bearing mesogenic 3,4,

Optoelectronic exploration of novel non-symmetrical star-shaped discotic liquid crystals based on cyanopyridine

A novel family of non-symmetrical star-shaped cyanopyridine based discotic liquid crystals (CPBz6, CPBz8 and CPBz12) was designed and synthesized, as potential luminescent materials for optoelectronic applications. The length of one of the arms in the design was systematically varied to determine the structure-property relationships. Evidently, all of the compounds exhibited a highly prospective ordered columnar mesomorphism stabilized at ambient temperature with advantageous very low isotropization temperatures. Furthermore, their photophysical characteristics were investigated in depth, both in solution and in the liquid crystal (LC) state. The discotics were found to be intense blue emitters with reasonably good quantum efficiency. Their dynamic intramolecular charge-transfer (ICT) behaviour was confirmed by steady-state absorption and fluorescence spectral analysis in varied solvent polarity. Furthermore, their electrochemical properties were studied from the combination of an experimental method and the theoretical simulations, which elucidated the low laying frontier molecular orbitals (FMOs) with a narrow energy band gap of ～2.0 eV. The resulted visually perceivable emission with favourable energy levels showcases their possible application in electronic display devices.

Hydrogen-bonding induced melamine-core supramolecular discotic liquid crystals

Recognition of melamine is not only of importance for the food industry but also an interesting scientific research topic. The objective of this work is to screen suitable hydrogen-bonding complementary compounds for the construction of melamine-core supr

Construction of dendrimers with a square-shaped core consisting of zinc chlorophyll assembly via intermolecular nitrogen-zinc coordination

The first dendrimers consisting of self-assembled zinc chlorophyll derivatives are reported. Coordination-directed self-assembly of pyridine-appended zinc chlorophyll derivatives tethering a dendron moiety results in cyclic tetramers peripherally function

Cyanuric acid derivatives, disc-shaped liquid crystal material and a melamine detection method

The invention discloses a cyanuric acid derivative, a disc-like liquid crystal material and a melamine detection method. The liquid crystal material is a cyanuric acid derivative which has the basic characteristics of cyanuric acid and can be connected wi

Synthesis and properties of hole-transporting triphenylamine-derived dendritic compounds

Materials based on triphenylamino core linked with different alkoxyphenyl-substituents through olefinic spacers were synthesised, and their thermal, photophysical and photoelectrical properties were investigated. The synthesized compounds showed relativel

Metalloenzyme-mimicking supramolecular catalyst for highly active and selective intramolecular alkyne carboxylation

Creation of synthetic catalysts with enzyme-like behavior is challenging despite strong interest in such systems. Extraction of tetrachloroaurate into the hydrophilic core of an interfacially cross-linked reverse micelle (ICRM) produced an artificial "metalloenzyme" with highly unusual catalytic properties. The ICRM pulled the substrate toward the catalytic metal, which converted it efficiently to the product that was rapidly ejected. These features enabled greatly reduced catalyst loading (30-100 times lower than typical levels used in literature examples), constant high reaction rate throughout the course of the reaction, lack of the hydrolyzed side product, and substrate selectivity unobserved in conventional gold catalysts.