molybdenum(V) fluoride

Base Information

• Chemical Name: molybdenum(V) fluoride
• CAS No.: 194303-41-8
• Molecular Formula: F₅Mo
• Molecular Weight: 190.932
• Mol file: 194303-41-8.mol

Synonyms:

Chemical Property of molybdenum(V) fluoride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of molybdenum(V) fluoride

There total 7 articles about molybdenum(V) fluoride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

molybdenum(VI) fluoride (7783-77-9) + phosphorus trichloride (7719-12-2,52843-90-0) → molybdenum(V) fluoride (13819-84-6,194303-41-8) + phosphorus pentafluoride (7647-19-0,874483-74-6) + chlorine (7782-50-5) + trifluorophosphane (7783-55-3) + molybdenum(IV) chloride (13320-71-3)

Guidance literature:

In not given; react. with an excess of MoF6 forming PF3, MoCl5 and Cl2; react. of MoCl5 forming MoCl4 and Cl2; further react. of MoF6 with PF3 forming PF5 and MoF5;;

DOI:10.1016/0022-1902(62)80185-7

Reference yield:

oxygen (80937-33-3) + fluorine (7782-41-4) + molybdenum (7439-98-7) → molybdenum(VI) fluoride (7783-77-9) + molybdenum tetrafluoride (23412-45-5) + molybdenum(V) fluoride (13819-84-6,194303-41-8) + molybdenum pentafluoride trimer + molybdenum oxotetrafluoride (14459-59-7,52049-90-8)

Guidance literature:

In gas; reacted in gas phase at 100-1100°C using F2 contg. ca. 1% O2; further products; not isolated, detected by IR in Ar matrice;

Reference yield:

nitrogen trifluoride (7783-54-2) + molybdenum (7439-98-7) → molybdenum(VI) fluoride (7783-77-9) + molybdenum(V) fluoride (13819-84-6,194303-41-8)

Guidance literature:

byproducts: N2; NF3 redn. by molybdenum incandescent filament in reaction vessel withoutinternal screen (pressure 0.2-0.4 atm, filament temp. 350-400°C, cooling. temp. 100-150°C); vac. distn. at 60°C; X-ray diffraction, gas chromy.;

upstream raw materials:

molybdenum(VI) fluoride

phosphorus trichloride

nitrogen trifluoride

molybdenum

Downstream raw materials:

molybdenum(VI) fluoride