ReH5(PMe2Ph)3

Base Information

• Chemical Name: ReH5(PMe2Ph)3
• CAS No.: 93712-84-6
• Molecular Formula: C₂₄H₃₈P₃Re
• Molecular Weight: 605.694
• Mol file: 93712-84-6.mol

Synonyms:

Chemical Property of ReH5(PMe2Ph)3

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

Useful:

Technology Process of ReH5(PMe2Ph)3

There total 4 articles about ReH5(PMe2Ph)3 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

cis-hydrido(dinitrogen)tetrakis(dimethylphenylphosphine)rhenium(I) (135707-77-6) → ReH5(PMe2Ph)3 (93712-84-6,92077-25-3,65816-70-8)

Guidance literature:

With hydrogen; In toluene; under nitrogen or Ar; H2 bubbled into the soln. for 7 h at room temp.; toluene removed under vac.; recrystn. (ether);

DOI:10.1021/om00055a024

Reference yield:

ReH4Al(CH3)2(P(C6H5)(CH3)2)3 → ReH5(PMe2Ph)3 (93712-84-6,92077-25-3,65816-70-8)

Guidance literature:

With H₂O; In water;

DOI:10.1021/ja00338a021

Reference yield:

mer-hydridobis(ethylene)tris(dimethylphenylphosphine)rhenium(I) (135707-76-5) → ReH5(PMe2Ph)3 (93712-84-6,92077-25-3,65816-70-8)

Guidance literature:

With hydrogen; In toluene; byproducts: ethylene, ethane; under nitrogen or Ar; at room temp., 192 h;

DOI:10.1021/om00055a024

upstream raw materials:

cis-hydrido(dinitrogen)tetrakis(dimethylphenylphosphine)rhenium(I)

mer-hydridobis(ethylene)tris(dimethylphenylphosphine)rhenium(I)

Downstream raw materials:

fac-ReCl₃(PMe₂Ph)3