cis-hydrido(dinitrogen)tetrakis(dimethylphenylphosphine)rhenium(I)

Base Information

• Chemical Name: cis-hydrido(dinitrogen)tetrakis(dimethylphenylphosphine)rhenium(I)
• CAS No.: 135707-77-6
• Molecular Formula: C₃₂H₄₅N₂P₄Re
• Molecular Weight: 767.825
• Mol file: 135707-77-6.mol

Synonyms:cis-hydrido(dinitrogen)tetrakis(dimethylphenylphosphine)rhenium(I)

Chemical Property of cis-hydrido(dinitrogen)tetrakis(dimethylphenylphosphine)rhenium(I)

Chemical Property:

Purity/Quality:

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Technology Process of cis-hydrido(dinitrogen)tetrakis(dimethylphenylphosphine)rhenium(I)

There total 1 articles about cis-hydrido(dinitrogen)tetrakis(dimethylphenylphosphine)rhenium(I) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 57.0%

mer-trichlorotris(dimethylphenylphosphine)rhenium(III) (14710-16-8,15613-32-8,24627-46-1) + Dimethyl(phenyl)phosphine (672-66-2) → cis-hydrido(dinitrogen)tetrakis(dimethylphenylphosphine)rhenium(I) (135707-77-6)

Guidance literature:

With N₂; n-propyllithium; In diethyl ether; under nitrogen; mixt. stirred for 2 h at room temp., hydrolyzed; recrystd. (ether); elem. anal.;

DOI:10.1021/om00055a024

Reference yield: 74.0%

cis-hydrido(dinitrogen)tetrakis(dimethylphenylphosphine)rhenium(I) (135707-77-6) + ethyl 2-cyanoacetate (105-56-6) → Re(P(CH3)2C6H5)4(NCCHCOOC2H5)(NCCH2COOC2H5)

Guidance literature:

In diethyl ether; byproducts: N2, H2; inert atmosphere; addn. of 3 equiv. of cyanoacetate to Re-complex soln.,stirring (room temp., 6 h); evapn., recrystn. (Et2O/hexane); isomer mixt. not sepd., detd. by (1)H- and (31)P-NMR spectroscopy; elem. anal.;

DOI:10.1016/S0022-328X(98)00768-2

Reference yield: 69.0%

cis-hydrido(dinitrogen)tetrakis(dimethylphenylphosphine)rhenium(I) (135707-77-6) + methyl 2-cyanoacetate (105-34-0) → Re(P(CH3)2C6H5)4(NCCHCOOCH3)(NCCH2COOCH3)

Guidance literature:

In diethyl ether; byproducts: N2, H2; inert atmosphere; addn. of 3 equiv. of cyanoacetate to Re-complex soln.,stirring (room temp., 6 h); evapn., recrystn. (Et2O/hexane); elem. anal.;

DOI:10.1016/S0022-328X(98)00768-2

upstream raw materials:

mer-trichlorotris(dimethylphenylphosphine)rhenium(III)

Dimethyl(phenyl)phosphine

Downstream raw materials:

mer-hydridobis(ethylene)tris(dimethylphenylphosphine)rhenium(I)

ReH₃{PMe₂Ph}4

ReH5(PMe2Ph)3

Re(P(CH₃)2C₆H₅)4(CH₃OOCCHCOOCH₃)