[ReRu2(μ-H)(μ-CO)2(μ3-CC6H5)(CO)6(η5-C5H5)]

Base Information

Chemical Name:[ReRu2(μ-H)(μ-CO)2(μ3-CC6H5)(CO)6(η5-C5H5)]
CAS No.:443783-05-9
Molecular Formula:C₂₀H₁₁O₈ReRu₂
Molecular Weight:767.65
Hs Code.:

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Chemical Property of [ReRu2(μ-H)(μ-CO)2(μ3-CC6H5)(CO)6(η5-C5H5)]

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Technology Process of [ReRu2(μ-H)(μ-CO)2(μ3-CC6H5)(CO)6(η5-C5H5)]

There total 2 articles about [ReRu2(μ-H)(μ-CO)2(μ3-CC6H5)(CO)6(η5-C5H5)] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 40.0%

: sodium tetracarbonylruthenate(II)

: [(η(5)-C5H5)(CO)2Re*CC6H5]BBr4

: 110-54-3
hexane

: sodium amide

: 443783-05-9
[ReRu2(μ-H)(μ-CO)2(μ3-CC6H5)(CO)6(η5-C5H5)]

: 871503-81-0
[η5-C5H5(CO)2Re=C(C6H5)NH2]

: [Re2Ru2(μ3-C(CC6H5)(μ-CC6H5))(μ-CO)(CO)8(η5-C5H5)2] * hexane

Guidance literature:: In tetrahydrofuran; (N2); Ru complex (contaminated with NaNH2) added to a soln. of Re complex cooled to -100°C, stirred at -100 to -50°C for 4 h; evapd. (vac., -45 to -40°C), chromd. (alumina, -25°C, petroleum ether/CH2Cl2, then petroleum ether/CH2Cl2/Et2O), evapd. (vac., -20°C), recrystd. (-80°C); elem. anal.;
DOI:10.1021/om058008a

Reference yield: 21.0%

: 97150-52-2
{bis(triphenylphosphine)nitrogen}2{Ru₃(CO)11}

: [(η(5)-C5H5)(CO)2Re*CC6H5]BBr4

: (Re(CO)2(C₅H₅)(CC₆H₅))2

: 443783-05-9
[ReRu2(μ-H)(μ-CO)2(μ3-CC6H5)(CO)6(η5-C5H5)]

Guidance literature:: In tetrahydrofuran; N2; addn. of Ru complex to soln. of freshly prepared Re complex in dry THF at -100°C, stirring for 4 h at temp. from -100 to -50°C; removing of solvent under vac. at -50 - -45°C, sepn. of the products on Al2O3 at -25°C with petroleum ether/CH2Cl2 (5:2 and 2:1) as eluant, removing of solvent under vac., recrystn. from petroleum ether/CH2Cl2 at -80°C, elem. anal.;
DOI:10.1021/om0201359