(η3-allyl-2κ3-C)(chloro-1κCl)(μ-N,N'-diethyldithioxamidato-1:2κ4-S,S':N,N')[diphenyl(2-pyridyl)phosphine-1κP]palladium(II)platinum(II) chloroform solvate

Base Information

• Chemical Name: (η3-allyl-2κ3-C)(chloro-1κCl)(μ-N,N'-diethyldithioxamidato-1:2κ4-S,S':N,N')[diphenyl(2-pyridyl)phosphine-1κP]palladium(II)platinum(II) chloroform solvate
• CAS No.: 446281-70-5
• Molecular Formula: CHCl₃*C₂₆H₂₉ClN₃PPdPtS₂
• Molecular Weight: 934.973
• Mol file: 446281-70-5.mol

Synonyms:

Chemical Property of (η3-allyl-2κ3-C)(chloro-1κCl)(μ-N,N'-diethyldithioxamidato-1:2κ4-S,S':N,N')[diphenyl(2-pyridyl)phosphine-1κP]palladium(II)platinum(II) chloroform solvate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η3-allyl-2κ3-C)(chloro-1κCl)(μ-N,N'-diethyldithioxamidato-1:2κ4-S,S':N,N')[diphenyl(2-pyridyl)phosphine-1κP]palladium(II)platinum(II) chloroform solvate

There total 2 articles about (η3-allyl-2κ3-C)(chloro-1κCl)(μ-N,N'-diethyldithioxamidato-1:2κ4-S,S':N,N')[diphenyl(2-pyridyl)phosphine-1κP]palladium(II)platinum(II) chloroform solvate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

bis(η3-allyl-μ-chloropalladium(II)) + chloroform (67-66-3,8013-54-5) + [(P(C6H5)2(C5H4N))ClPt(H(C2H5)2N2C2S2)] → (η3-allyl-2κ3-C)(chloro-1κCl)(μ-N,N'-diethyldithioxamidato-1:2κ4-S,S':N,N')[diphenyl(2-pyridyl)phosphine-1κP]palladium(II)platinum(II) chloroform solvate (446281-70-5)

Guidance literature:

In methanol; chloroform; (Pd(C3H5)Cl)2 dissolved in CH3OH/CHCl3 (70/30), reacted with (P(C6H5)2(C5H4N))ClPt(H(C2H5)2N2S2C2 (0.5 equiv.), soln. allowed to stand for 2 h; solvent removed, dissolved in CHCl3, column chromy. (alumina, equilibrated with light petroleum), concd., pptn. by addn. of petroleum ether, recrystd. from chloroform; elem. anal.;

DOI:10.1107/S0108270102006303

Reference yield:

[(P(C6H5)2(C5H4N))ClPt(H2(C2H5)2N2C2S2)](1+)*Cl(1-)=[(P(C6H5)2(C5H4N))ClPt(H2(C2H5)2N2C2S2)]Cl (281225-74-9) → (η3-allyl-2κ3-C)(chloro-1κCl)(μ-N,N'-diethyldithioxamidato-1:2κ4-S,S':N,N')[diphenyl(2-pyridyl)phosphine-1κP]palladium(II)platinum(II) chloroform solvate (446281-70-5)

Guidance literature:

Multi-step reaction with 2 steps

1: sodium bicarbonate / chloroform

2: chloroform; methanol

With sodium bicarbonate; In methanol; chloroform;

DOI:10.1107/S0108270102006303

upstream raw materials:

chloroform

[(P(C₆H₅)2(C₅H₄N))ClPt(H₂(C₂H₅)2N₂C₂S₂)]⁽¹⁺⁾*Cl^(1-)=[(P(C₆H₅)2(C₅H₄N))ClPt(H₂(C₂H₅)2N₂C₂S₂)]Cl