silver 4-ethylbenzoate

Base Information

• Chemical Name: silver 4-ethylbenzoate
• CAS No.: 870814-23-6
• Molecular Formula: Ag*C₉H₉O₂
• Molecular Weight: 257.037
• Mol file: 870814-23-6.mol

Synonyms:

Chemical Property of silver 4-ethylbenzoate

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of silver 4-ethylbenzoate

There total 1 articles about silver 4-ethylbenzoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 45.0%

p-ethylbenzoic acid (619-64-7) + silver carbonate → silver 4-ethylbenzoate (870814-23-6)

Guidance literature:

In acetonitrile; soln. 4-ethylbenzoic acid in MeCN was added dropwise at room temp. to suspn. Ag2CO3 in MeCN and refluxed for 7 h; react. mixt. was cooled to room temp., ppt. was filtered, suspended in water and refluxed, hot filtration and evapn. to dryness; elem. anal.;

DOI:10.1021/ic050975q

Reference yield: 84.0%

trichloro(4'-(4-(N,N-di-n-butylaminamino)phenyl)-2,2':6',2''-terpyridine)iridium(III) (443286-03-1) + silver 4-ethylbenzoate (870814-23-6) → [Ir(4-ethylbenzoate)3(4'-(phenyl-p-dibutylamino)-2,2':6',2''-terpyridine)] (870814-16-7) + silver(I) chloride

Guidance literature:

In chloroform; 4-EtC6H4COOAg was added to soln. Ir complex in CHCl3 and stirred at roomtemp. for 24 h; soln. was filtered and evapd. to dryness; elem. anal.;

DOI:10.1021/ic050975q

Reference yield: 78.0%

4'-[4-(N,N-dihexadecylamino)phenyl]-2,2':6',2''-terpyridine + RuCl3(4'-(C6H4-p-N(C16H33)2)-2,2':6',2''-terpyridine) (1377788-38-9) + silver 4-ethylbenzoate (870814-23-6) → [Ru(4'-(C6H4-p-N(C16H33)2)-2,2':6',2''-terpyridine)2][4-EtC6H4COO]2

Guidance literature:

With N-ethylmorpholine; In ethanol; byproducts: AgCl; soln. ligand in abs EtOH and 5 drops N-ethylmorpholine was added to soln. Ru complex in abs. EtOH, refluxed for 1 h, soln. was filtered hot through Celite, soln. 4-EtC6H4COOAg in hot EtOH was added, stirred at room temp. overnight; soln. was filtered through Celite and evapd.; elem. anal.;

DOI:10.1039/c2dt30183k

upstream raw materials:

p-ethylbenzoic acid

Downstream raw materials:

[Ir(4-ethylbenzoate)3(4'-(phenyl-p-dibutylamino)-2,2':6',2''-terpyridine)]

[Ir(4-ethylbenzoate)3(4'-(phenyl-p-nitro)-2,2':6',2''-terpyridine)]