trichloro(4'-(4-(N,N-di-n-butylaminamino)phenyl)-2,2':6',2''-terpyridine)iridium(III)

Base Information

• Chemical Name: trichloro(4'-(4-(N,N-di-n-butylaminamino)phenyl)-2,2':6',2''-terpyridine)iridium(III)
• CAS No.: 443286-03-1
• Molecular Formula: C₂₉H₃₂Cl₃IrN₄
• Molecular Weight: 735.179
• Mol file: 443286-03-1.mol

Synonyms:

Chemical Property of trichloro(4'-(4-(N,N-di-n-butylaminamino)phenyl)-2,2':6',2''-terpyridine)iridium(III)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trichloro(4'-(4-(N,N-di-n-butylaminamino)phenyl)-2,2':6',2''-terpyridine)iridium(III)

There total 2 articles about trichloro(4'-(4-(N,N-di-n-butylaminamino)phenyl)-2,2':6',2''-terpyridine)iridium(III) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 35.0%

iridium(III) chloride hydrate + 4'-(4-(N,N-di-n-butylaminamino)phenyl)-2,2':6',2''-terpyridine (443286-05-3) → trichloro(4'-(4-(N,N-di-n-butylaminamino)phenyl)-2,2':6',2''-terpyridine)iridium(III) (443286-03-1)

Guidance literature:

In ethanol; soln. ligand in EtOH was added to soln. IrCl3*xH2O in EtOH, refluxed for6 h, and stirred at room temp. overnight; ppt. was filtered, dissolved in CH2Cl2, filtered and evapd. to dryness; elem. anal.;

DOI:10.1021/ic050975q

Reference yield:

iridium (III) chloride (10025-83-9) + 4'-(4-(N,N-di-n-butylaminamino)phenyl)-2,2':6',2''-terpyridine (443286-05-3) → trichloro(4'-(4-(N,N-di-n-butylaminamino)phenyl)-2,2':6',2''-terpyridine)iridium(III) (443286-03-1)

Guidance literature:

In not given; react. stoich. amnts. IrCl3, 4'-(4-(N,N-di-n-butylaminamino)phenyl)-2,2':6',2''-terpyridine;

DOI:10.1039/b201221a

Reference yield: 84.0%

trichloro(4'-(4-(N,N-di-n-butylaminamino)phenyl)-2,2':6',2''-terpyridine)iridium(III) (443286-03-1) + silver 4-ethylbenzoate (870814-23-6) → [Ir(4-ethylbenzoate)3(4'-(phenyl-p-dibutylamino)-2,2':6',2''-terpyridine)] (870814-16-7) + silver(I) chloride

Guidance literature:

In chloroform; 4-EtC6H4COOAg was added to soln. Ir complex in CHCl3 and stirred at roomtemp. for 24 h; soln. was filtered and evapd. to dryness; elem. anal.;

DOI:10.1021/ic050975q

upstream raw materials:

4'-(4-(N,N-di-n-butylaminamino)phenyl)-2,2':6',2''-terpyridine

iridium (III) chloride

Downstream raw materials:

[Ir(4-ethylbenzoate)3(4'-(phenyl-p-dibutylamino)-2,2':6',2''-terpyridine)]