{Rh(HOC₆H₄COO)(1,5-cyclooctadiene)}2

Base Information

• Chemical Name: {Rh(HOC₆H₄COO)(1,5-cyclooctadiene)}2
• CAS No.: 149095-10-3
• Molecular Formula: C₃₀H₃₄O₆Rh₂
• Molecular Weight: 696.407
• Mol file: 149095-10-3.mol

Synonyms:

Chemical Property of {Rh(HOC₆H₄COO)(1,5-cyclooctadiene)}2

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of {Rh(HOC₆H₄COO)(1,5-cyclooctadiene)}2

There total 2 articles about {Rh(HOC₆H₄COO)(1,5-cyclooctadiene)}2 which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 80.0%

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium (12092-47-6) → {Rh(HOC6H4COO)(1,5-cyclooctadiene)}2 (149095-10-3)

Guidance literature:

With HOC₆H₄COOAg; In n-heptane; byproducts: AgCl; stirring Rh-compd. and HOC6H4COOAg in heptane (room temp., 2 h), pptn. of AgCl; filtration (sepn. of ppt.), washing of ppt. (heptane), concn. of of filtrates (evapn.), pptn., filtration off, drying (vac.);

DOI:10.1016/0304-5102(93)85077-7

Reference yield: 80.0%

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium (12092-47-6) + silver salicylate (528-93-8,14800-64-7) → di-(μ-salicylato-O,O')-bis(1,5-cyclooctadiene)dirhodium(I) (149095-10-3)

Guidance literature:

In n-heptane; byproducts: AgCl; stirred at room temp. for 2 h;; filtered; washed with heptane; filtrate and washings evapd.; dried in vacuo; identified by single crystal x-ray diffraction;;

DOI:10.1016/S0277-5387(00)84742-7

Reference yield: 78.0%

{Rh(HOC6H4COO)(1,5-cyclooctadiene)}2 (149095-10-3) → 2Rh(1+)*4CO*2HOC6H4COO(1-)={Rh(HOC6H4COO)(CO)2}2

Guidance literature:

With carbon monoxide; In hexane; saturation with CO; pptn. on concn. (vac.), filtration off, drying (vac.); elem. anal.;

DOI:10.1016/0304-5102(93)85077-7

upstream raw materials:

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

silver salicylate