Technology Process of C27H31N3OSi
There total 11 articles about C27H31N3OSi which
guide to synthetic route it.
The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:
synthetic route:
- Guidance literature:
-
With
sodium azide;
In
N,N-dimethyl-formamide;
at 80 ℃;
for 8h;
DOI:10.1002/ejoc.201402157
- Guidance literature:
-
Multi-step reaction with 6 steps
1.1: 1H-imidazole / dichloromethane / 1.17 h / 0 - 20 °C
2.1: oxalyl dichloride; dimethyl sulfoxide / dichloromethane / 3 h / -78 - 20 °C
2.2: 2 h / 25 °C
3.1: lithium hexamethyldisilazane / tetrahydrofuran / 0.75 h / 0 °C
3.2: 23 °C
4.1: camphor-10-sulfonic acid / methanol / 0 °C
5.1: triethylamine; dmap / dichloromethane / 1 h / 0 - 20 °C
6.1: sodium azide / N,N-dimethyl-formamide / 8 h / 80 °C
With
1H-imidazole; dmap; sodium azide; oxalyl dichloride; camphor-10-sulfonic acid; dimethyl sulfoxide; triethylamine; lithium hexamethyldisilazane;
In
tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide;
2.1: |Swern Oxidation / 2.2: |Swern Oxidation;
DOI:10.1002/ejoc.201402157
- Guidance literature:
-
Multi-step reaction with 4 steps
1.1: lithium hexamethyldisilazane / tetrahydrofuran / 0.75 h / 0 °C
1.2: 23 °C
2.1: camphor-10-sulfonic acid / methanol / 0 °C
3.1: triethylamine; dmap / dichloromethane / 1 h / 0 - 20 °C
4.1: sodium azide / N,N-dimethyl-formamide / 8 h / 80 °C
With
dmap; sodium azide; camphor-10-sulfonic acid; triethylamine; lithium hexamethyldisilazane;
In
tetrahydrofuran; methanol; dichloromethane; N,N-dimethyl-formamide;
DOI:10.1002/ejoc.201402157
