trans-bis(1,1-diethyl-3-thiobenzoylthioureato) nickel(II)

Base Information

• Chemical Name: trans-bis(1,1-diethyl-3-thiobenzoylthioureato) nickel(II)
• CAS No.: 99265-63-1
• Molecular Formula: C₂₄H₃₀N₄NiS₄
• Molecular Weight: 561.483
• Mol file: 99265-63-1.mol

Synonyms:

Chemical Property of trans-bis(1,1-diethyl-3-thiobenzoylthioureato) nickel(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-bis(1,1-diethyl-3-thiobenzoylthioureato) nickel(II)

There total 12 articles about trans-bis(1,1-diethyl-3-thiobenzoylthioureato) nickel(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 74.0%

sodium tetrahydroborate (16940-66-2) + 3-diethylamino-5-phenyl-1,2,4-dithiazolium tetrachloroniccolate(II) → cis-bis(1,1-diethyl-3-thiobenzoylthioureato) nickel(II) (99265-63-1,118713-33-0,80347-15-5)

Guidance literature:

In pyridine; acetonitrile; addn. of NaBH4 to soln. of Ni-compd. in MeCN and pyridine, stirring (2 h, room temp.); crystn. (overnight, refrigerator), dissoln. (CHCl3), pptn. on addn. of EtOH;

Reference yield: 74.0%

sodium tetrahydroborate (16940-66-2) + nickel(II) perchlorate hexahydrate + 3-diethylamino-5-phenyl-1,2,4-dithiazolium perchlorate (65407-92-3) → cis-bis(1,1-diethyl-3-thiobenzoylthioureato) nickel(II) (99265-63-1,118713-33-0,80347-15-5)

Guidance literature:

In pyridine; acetonitrile; addn. of NaBH4 to soln. of org. compd. and Ni-compd. in MeCN and pyridine, stirring (2 h, room temp.); crystn. (overnight, refrigerator), dissoln. (CHCl3), pptn. on addn. of EtOH;

Reference yield: 12.0%

nickel(II) tetrafluoroborate hexahydrate + N-diethylaminothiocarbonylbenzimidoyl chloride → cis-bis(1,1-diethyl-3-thiobenzoylthioureato) nickel(II) (99265-63-1,118713-33-0,80347-15-5)

Guidance literature:

With triethylamine; ethane-1,2-dithiol; In acetonitrile; byproducts: (C2H5)3NH4Cl, (C2H5)3NHBF4, (SCH2CH2)2; dithiol is added in one portion to a soln. of Ni(BF4)2*6H2O, dropwise addn. of benzimidoylchloride (dissolved in MeCN with slight warming) within 30 min., after further 30 min. slow addn. of NEt3, stirring for 20 h at room temp.; concn., cooling (0°C), ppt. is sucked off, extd. (CH2Cl2, 3 times), extracts are concd., addn of ethanol, crystals form overnight in refrigerator, recrystn. (CH2Cl2/C2H5OH);

upstream raw materials:

sodium tetrahydroborate

3-diethylamino-5-phenyl-1,2,4-dithiazolium perchlorate

N-[(diethylamino)carbonothioyl]benzenecarboximidoyl chloride

ethane-1,2-dithiol

Downstream raw materials:

bis(1,1-diethyl-3-thiobenzoyl-thioureato)nickel(II)

(1,1-diethyl-3-thiobenzoyl-thioureato)(diethyldiselenocarbamato)copper(II)