[Pt(Cl)(CNCH₂CO₂Et)(PPh₃)2]BF₄

Base Information

• Chemical Name: [Pt(Cl)(CNCH₂CO₂Et)(PPh₃)2]BF₄
• CAS No.: 150196-78-4
• Molecular Formula: BF₄*C₄₁H₃₇ClNO₂P₂Pt
• Molecular Weight: 955.035

Synonyms:

Chemical Property of [Pt(Cl)(CNCH₂CO₂Et)(PPh₃)2]BF₄

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [Pt(Cl)(CNCH₂CO₂Et)(PPh₃)2]BF₄

There total 1 articles about [Pt(Cl)(CNCH₂CO₂Et)(PPh₃)2]BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

di-μ-chlototetrakis(triphenylphosphine)diplatinum(II) tetrafluoroborate + Ethyl isocyanoacetate (2999-46-4) → PtCl(P(C6H5)3)2(CNCH2COOCH2CH3)(1+)*BF4(1-)=PtCl(P(C6H5)3)2(CNCH2COOCH2CH3)(BF4) (57677-02-8,150196-78-4)

Guidance literature:

In chloroform; dropwise addn. of a soln. of isonitrile in CHCl3 to a suspn. of Pt complex in CHCl3; filtration through Celite, concn. in vac., layering with Et2O, cooling to 0°C, washing crystald with ether, drying in vac.; elem. anal.;

DOI:10.1002/zaac.200700540

Reference yield: 80.0%

hexafluoroacetone sesquihydrate + PtCl(P(C6H5)3)2(CNCH2COOCH2CH3)(1+)*BF4(1-)=PtCl(P(C6H5)3)2(CNCH2COOCH2CH3)(BF4) (57677-02-8,150196-78-4) → [Pt(Cl)(C(=O)NHCH2CO2Et)(PPh3)2]

Guidance literature:

With triethylamine; In dichloromethane; addn. of amine and ketone to a soln. of Pt complex in CH2Cl2, standing in the dark for 1 d; evapn. in vac., recrystn. (CH2Cl2/acetone, Et2O); elem. anal.;

DOI:10.1002/zaac.200700540

Reference yield: 69.0%

di-μ-chlototetrakis(triphenylphosphine)diplatinum(II) tetrafluoroborate + [Pt(Cl)(CNCH2CO2Et)(PPh3)2]BF4 (57677-02-8,150196-78-4) → (μ-CNCH(CO2Et))(cis-PtCl(PPh3)2)2

Guidance literature:

With KOtBu; In dichloromethane; under Ar; Pt complexes and KOtBu suspended in CH2Cl2, stirred for 2 h atroom temp.; solvent removed; residue stirred in ethyl ether for 12 h; collected on frit, dried at 40.degree,C in high vac.; recrystd. from CH2Cl2/ether; elem. anal.;

DOI:10.1002/zaac.200900531

upstream raw materials:

Ethyl isocyanoacetate

Post a RFQ

Cas No.:

Product Name:

Quantity:

Please select Metric Ton KG G Pound L ML

Email:

Company name:

Valid Period:

Detailed Requirements:

• Sample
• MOQ
• GMP
• FDA
• Price
  FOB CIF CFR EXW
• Urgent purchase

Enter 15 to 2000 letters.Word count: 0 letters

Attach files(File Format: Jpeg, Jpg, Gif, Png, PDF, PPT, Zip, Rar,Word or Excel Maximum File Size: 3MB)

Remove

Submit

1

What can I do for you?
Get Best Price

Get Best Price for 150196-78-4 [Pt(Cl)(CNCH₂CO₂Et)(PPh₃)2]BF₄

Send

Send

Metric Ton KG G Pound L ML

Send

Send