[1,3-bis(2,4,6-trimethylphenyl)imidazolium][(cyclopentadienylVCl₃]

Base Information

• Chemical Name: [1,3-bis(2,4,6-trimethylphenyl)imidazolium][(cyclopentadienylVCl₃]
• CAS No.: 1227471-29-5
• Molecular Formula: C₅H₅Cl₃V*C₂₁H₂₅N₂
• Molecular Weight: 527.838
• Mol file: 1227471-29-5.mol

Synonyms:

Chemical Property of [1,3-bis(2,4,6-trimethylphenyl)imidazolium][(cyclopentadienylVCl₃]

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of [1,3-bis(2,4,6-trimethylphenyl)imidazolium][(cyclopentadienylVCl₃]

There total 2 articles about [1,3-bis(2,4,6-trimethylphenyl)imidazolium][(cyclopentadienylVCl₃] which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

hydrogenchloride (7647-01-0,15364-23-5) + (cyclopentadienyl)VCl2(1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene) → [1,3-bis(2,4,6-trimethylphenyl)imidazolium][(cyclopentadienylVCl3] (1227471-29-5)

Guidance literature:

In tetrahydrofuran; 1,4-dioxane; (Ar or N2); addn. of HCl in dioxane to a soln. of vanadium complex in THF at -35°C;

DOI:10.1039/b922744j

Reference yield: 45.0%

hydrogenchloride (7647-01-0,15364-23-5) + vanadocene monochloride + 1,3-bis(mesityl)imidazolium chloride (141556-45-8) → [1,3-bis(2,4,6-trimethylphenyl)imidazolium][(cyclopentadienylVCl3] (1227471-29-5)

Guidance literature:

In tetrahydrofuran; 1,4-dioxane; byproducts: cyclopentadiene; (Ar or N2); dissolving a mixt. of vanadium complex and ligand in THF, reflux for 1.5 h, filtration, cooling to -35°C, dropwise addn. of HCl in dioxane, warming to room temp.; concn. in vac., layering with toluene, standing for 7 d, filtration, washing with cold THF; elem. anal.;

DOI:10.1039/b922744j

upstream raw materials:

hydrogenchloride

1,3-bis(mesityl)imidazolium chloride